British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
there must be instability, where the bonding material of the internal
particles of the glass is in different states of hardness; so that
there is no difficulty in conceiving how a gas globe could break
apparently spontaneously, for a portion of it which was not fairly
toughened might be exposed to a somewhat sudden rise of temperature,
produced, it may be, from a draught blowing the flame upon that
particular spot. Articles such as saucers, made of glass, which, being
flat, or nearly so, can be plunged into the tempering liquid with
great rapidity, are usually tempered all over, and these, when
toughened, can be thrown about and allowed to fall on hard floors with
impunity, thus proving the facts which I have endeavoured to
establish. I hope to be able to continue my investigations, and should
they be worth anything, will give the results of them to the public.
Before quitting this subject, I shall make a few remarks upon the
process for toughening glass, which is said to have been purchased by
the Prussian Government.
This process is described as consisting in the application of
superheated steam to the glass, brought up to a temperature near to
its melting point. Having facilities for making experiments of this
kind, I have had them tried with great care, but in no case have I met
with a satisfactory result. This probably is owing to the fact, that I
did not comply strictly with the condition of the experiments
performed by the German chemist who is said to have made the
invention, nor do I see from analogy how this process is likely to
effect a change in the glass similar to that arising from M. de la
Bastie's dipping process.
If glass, instead of being taken from the annealing kiln at the proper
time, be left exposed in the hot part of it, at a temperature just
below that at which it softens, it will be found to become gradually
opaque on its surface. Some experiments were performed many years ago
by RA(C)aumur, who exposed pieces of glass, packed in plaster of Paris,
to a red heat, which became gradually opaque, and lost altogether the
character of glass, the texture of their material becoming
crystalline, and also effected by sudden changes of temperature. Glass
treated in this way was called RA(C)aumur's porcelain. All glasses do not
undergo this change with equal rapidity, and some do not experience it
at all; but the commoner kinds, such as bottle glass, are the best to
experiment upon, for the more alumina that it contains--and it is
known that bottle glass contains a considerable quantity--the more
readily does it undergo this change, which is called _devitrification_.
In what it consists, is not at present well understood, but it offers
a field for investigation, which may produce results of very
considerable benefit to manufacturers of glass.
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