Buffon's Natural History. Volume 10 (of 10): Containing a Theory of the Earth, a General History of Man, of the Brute Creation, and of Vegetables, Minerals, &c. &cBuffon, Georges Louis Leclerc, comte de
History
Buffon's Natural History. Volume 10 (of 10): Containing a Theory of the Earth, a General History of Man, of the Brute Creation, and of Vegetables, Minerals, &c. &c
Buffon, Georges Louis Leclerc, comte de
Natural history
The progress and duration of heat in metals does not then follow the
order of their density, except in tin, which being the least dense,
is also that which soonest loses its heat; but the order of the five
other metals demonstrates that it is in relation to their fusibility
that they all receive and loose heat; for iron is more difficult to
melt than copper, copper more than gold, gold more than silver, silver
more than lead, lead more than tin; and therefore we may conclude that
it is only by chance if the density and fusibility of tin be found
so united as to place it in the last rank. Nevertheless, it would be
advancing too much to pretend that we must attribute all to fusibility,
and nothing to density. Nature never deprives herself of one of her
properties in favour of another in an absolute manner; that is to say,
in a mode that the first has not any influence on the second. Thus,
density may be of some weight in the progress of heat; but we may
safely affirm, that in the six metals it has very little comparatively
with fusibility.
This fact was neither known to chemists nor naturalists; they did not
even imagine that gold which is more than twice as dense as iron,
nevertheless loses its heat near a third sooner. It is the same with
lead, silver, and copper, which are all more dense than iron, and
which, like gold, heat and cool more readily; for though the object of
this, second memoir was only refrigeration, yet the experiments of the
one that preceded it demonstrate, that there is ingress and egress of
heat in bodies, and that those which receive it most quickly also lose
it the soonest.
If we reflect on the real principles of density, and the cause of
fusibility, we shall perceive, that density depends absolutely on the
quantity of matter which Nature places in a given space; that the more
she can make it enter therein, the more density there will be, and
that gold, in this respect, is of all substances, that which contains
the most matter relatively to its volume. It is for this reason that
it has been hitherto thought, that more time is required to heat or
cool gold than other metals; and it is natural enough to suppose, that
containing double or treble the matter in the same volume, double or
treble time would be required to penetrate it with heat; nay this would
be true, if in every substance the constituent parts were of the same
figure and ranged the same. But in the most dense the molecules of
matter are, probably, of a figure sufficiently regular not to leave
very void places between them; in others which are not so dense, and
their figures more irregular, more vacuities are left, and in the
lightest, the molecules being few, and most likely of a very irregular
figure, a thousand times more void is found than plenitude; for it may
be demonstrated by other experiments, that the volume of even the most
dense substance contains more void space than full matter.
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