Since chlorine was prepared at Edgewood, it was logical that some of
this chlorine should be utilized in the preparation of sulfur chloride.
The plant constructed consisted of 30 tanks (78 inches in diameter and
35 feet long), each capable of producing 20,000 pounds of monochloride
per day. The tanks are partially filled with sulfur and chlorine passed
in. The reaction proceeds rapidly with sufficient heat to keep the
sulfur in a molten condition. If the chlorine is passed in too rapidly,
the heat generated may be sufficient to boil off the sulfur chloride
formed. Hence water pipes are provided so that a supply of cold water
may be sprayed upon the tanks, keeping the temperature within the
proper limits.
[Illustration: FIG. 31.—Row of Furnaces for the Preparation of
Ethylene.]
In the manufacture of one ton of mustard gas, about one ton of sulfur
chloride and a little less than half a ton of ethylene (12,640 cubic
feet) are required.
GERMAN METHOD OF MANUFACTURE[19]
[Illustration: FIG. 32.—Preparation of Ethylene at Badische Anilin und
Soda Fabrik. 60 units.]
[Footnote 19: Norris, _J. Ind. Eng. Chem._, =11=, 821 (Sept., 1919).]
“PREPARATION OF ETHYLENE—The gas was
prepared by passing alcohol vapor over aluminum oxide
at a temperature of 380° to 400°. The details of the
construction of one of the furnaces are given in Figs.
32 and 33. The furnaces were very small and sixty units
were needed to furnish the amount of gas required. The
tubes containing the catalyzer were made of copper and
were heated in a bath of molten potassium nitrate. It
was stated that the catalyzer was made according to the
directions of Ipatieff, and that its life was from 10
to 20 days. The gas produced was washed in the usual
form of scrubber. The yield of ethylene was stated to
be about 90 per cent of the theoretical.
[Illustration: FIG. 33.—Ethylene Production at Badische Anilin und Soda
Fabrik. 1 unit.]
[Illustration: FIG. 34.—Chlorhydrin reaction kettle at Badische Anilin
und Soda Fabrik. 16 units.]
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