=Ammonia.= Ammonia respirators were needed by the Navy and also by
the workmen in refrigeration plants. Early protection was obtained by
the use of pumice stone impregnated with sulfuric acid. This had many
disadvantages, such as the amount of heat evolved, the caustic fumes
produced, high resistance and corrosion of the canister. To overcome
these, the “Kupramite” canister was developed. The filling consists of
pumice stone impregnated with copper sulfate. Pumice stone, 8 to 14
mesh, and technical copper sulfate are placed in an evaporating pan
in the ratio of one part by weight CuSO₄·5H₂O to 1.5 parts pumice,
and the whole is covered with sufficient water to dissolve the salt
at boiling temperature. The mixture is then boiled down with constant
stirring until crystallization takes place on the pumice and the
crystals are nearly dry. The pumice thus treated is then removed from
the dish, spread out and allowed to dry in the air. The fines are then
screened out on a 14-mesh sieve. Care must be taken in the evaporating
process that the absorbent is still slightly moist when taken from the
pan.
[Illustration: FIG. 64.—Early Type Navy Mask. Contains noseclip and
mouthpiece.]
In packing the standard Army canister with kupramite a layer of
toweling is placed on top of the absorbent to filter out any fine
particles which might be drawn up from the absorbent, and the whole is
held in place by the usual heavy wire screen and spring. This method of
packing is to be used with the present mouthpiece type of army mask.
If the new Tissot type mask is used, a modification of the packing is
desirable in order to eliminate the trouble due to moisture given off
by the absorbent during service condensing on the eyepieces of the mask
and thus impairing the vision of the wearer. To remedy this defect a
1-in. layer of kupramite at the top of the canister is replaced by
activated charcoal or silica gel, preferably silica gel. This decreases
the humidity of the effluent air sufficiently to prevent dimming of the
eyepieces. If charcoal is used, a 2-8 cotton pad (Eastern Star Furrier
Co., Pawtucket, R. I.) is substituted for the toweling in order to
remove charcoal dust. The canister complete weighs about 1.7 lbs.
[Illustration: FIG. 65.—Ammonia Canister—“Kupramite.”]
A canister containing 45 cu. in. of this material will protect a man
breathing at rest for at least 5 hours against 2 per cent ammonia and
for 2½ hours against 5 per cent ammonia. Its advantages are large
capacity and activity, negligible heat of absorption, and cheapness.
PHYSIOLOGICAL FEATURES OF THE MASK
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