The absorbents used in both the British and American gas mask canister,
which afforded a degree of protection far superior to that of any
other allied or enemy nation except Germany, consisted of a mixture
of charcoal and soda-lime, as described in the preceding chapter. In
general, a gas mask absorbent must have certain requirements. These
are: absorptive activity, absorptive capacity, versatility, mechanical
strength, chemical stability, low breathing resistance, ease of
manufacture and availability of raw materials.
[Footnote 27: The basis of this chapter is the series of articles by
Lamb and co-workers which appeared in the _J. Ind. Eng. Chem._ for
1919.]
_Absorptive activity_, or a very high rate of absorption, is one of
the more important properties of a satisfactory absorbent. A normal
man when exercising violently breathes about 60 liters of air per
minute, and since inhalation occupies but slightly more than half of
the breathing cycle, the actual rate at which gas passes through the
canister during inhalation is about 100 liters per minute. Calculated
on the basis of the regular army canister, this corresponds to an
average linear air velocity of about 80 cm. per second. On the average,
therefore, a given small portion of the air remains in contact with
the gas absorbent for only about 0.1 second. Besides this, the removal
of the toxic material must be surprisingly complete. Though the
concentration entering the canister may occasionally be as high as one
half per cent, even the momentary leakage of 0.001 per cent (ten parts
per million) would cause serious discomfort and the prolonged leakage
of smaller amounts would have serious results in the case of some
gases. The activity of the present gas mask charcoal is shown by the
fact that it will reduce a concentration of 7000 parts per million of
chloropicrin to less than 0.5 part per million in less than 0.03 second.
Of equal importance is the _absorptive capacity_. That is, the
absorbent must be able to absorb and hold large amounts of gas per
unit weight of absorbent. Its life must be measured in days against
ordinary concentrations of gas. It is further necessary that the gas
be held firmly and not in any loose combination which might give up
minute traces of gas when air is, for long periods of time, breathed in
through a canister which has previously been exposed to gas.
The absorbents used must be of a type which can be relied upon to
give adequate protection against practically any kind of toxic gas
(_versatility_). The need of this is apparent when the difficulty of
having separate canisters for various gases is considered, as well
as the difficulty in rapidly and accurately identifying the gases
and the possible introduction of new and unknown gases. Fortunately,
practically all of the toxic gases are very reactive chemically or have
relatively high boiling points and can therefore be absorbed in large
amounts by charcoal.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account