The first charcoal designed to offer protection against chlorine and
phosgene was made by carbonizing red cedar. Since this had little value
against chloropicrin, attention was turned to cocoanut shell as the
source of raw material. This charcoal fulfilled the above conditions
for a satisfactory absorbent better than any other form tested. It must
not be supposed, however, that investigation of carbon stopped with
these experiments. In the search for the ideal carbon, practically
almost every hard vegetable substance known was tested. Next to
cocoanut shells, the fruit pits, several common varieties of nuts
abundant in the United States, and several tropical nuts (especially
cohune nuts), were found to make the best carbon. Pecan nuts, and all
woods ranging in hardness from iron wood down to ordinary pine and
fir, were found to be in the second class of efficiency. Among other
substances tested were almonds, Arabian acorns, grape seeds, Brazil
nut husks, balsa, osage orange, Chinese velvet bean, synthetic carbons
(from coal, lamp-black, etc.), cocoa bean shell, coffee grounds, flint
corn, corn cobs, cotton seed husks, peanut shells and oil shale. While
many of these substances might have been used in an emergency, none of
them would produce carbon as efficient, volume for volume, as that of
the cocoanut shell and other hard nuts.
[Footnote 28: Bancroft (_J. Phys. Chem._ =24=, 127, 201, 342 [1920])
gives a comprehensive review of “Charcoal before the War.”]
[Footnote 29: Part of this section is quoted from “Armies of Industry,”
by Crowell and Wilson, Yale Univ. Press.]
Some idea of the scale of charcoal production may be seen from the
requirement for cocoanut shells. When we first began to build masks our
demands for carboniferous materials ranged from 40 to 50 tons a day
of raw material; by the end of the war, we were in need of a supply
of 400 tons of cocoanut shells per day. This demand would absorb the
entire cocoanut production of tropical America five times over. (The
total production of cocoanuts in Central America, the West Indies and
the Caribbean Coast of South America amounted to 131,000,000 nuts
annually, equal to a supply of 75 tons of shells daily.) It was equal
to one-tenth of the total production of the Orient, which amounted to
7,450,200,000 nuts annually. This large demand always made a reserve
supply of charcoal material practically impossible. The “Eat More
Cocoanut” campaign started by the Gas Defense more than doubled the
American consumption of cocoanut in a brief space of time and in
October, 1918, with the help of importation of shell, we averaged about
150 tons of shells per day, exclusive of the Orient.
Public-domain text, read in full here on John Shaqi.
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