Charcoal is not a satisfactory all-round absorbent because it has
too little capacity for certain highly volatile acid gases, such
as phosgene and hydrocyanic acid, and because oxidizing agents are
needed for certain gases. To overcome these deficiencies the use of
an alkali oxidizing agent in combination with the charcoal has been
found advisable. The material actually used for this purpose has been
granules of soda-lime containing sodium permanganate. Its principal
function may be said to be to act as a reservoir of large capacity for
the permanent fixation of the more volatile acid and oxidizable gases.
The development of a satisfactory soda-lime was a difficult problem.
The principal requirements follow: Its _activity_ is not of vital
importance, as the charcoal is able to take up gas with extreme
rapidity and then later give it off more slowly to the soda-lime.
_Absorptive capacity_ is of the greatest importance, since the
soda-lime is relied upon to hold in chemical combination a very
large amount of toxic gas. Both _chemical stability_ and _mechanical
strength_ are difficult to attain. The latter had never been solved
until the war made some solution absolutely imperative.
COMPOSITION OF REGULAR ARMY SODA-LIME
The exact composition of the army soda-lime has undergone considerable
modification from time to time as it has been found desirable to change
the raw materials or the method of manufacture. A rough average formula
which will serve to bring out the interrelation between the different
constituents is as follows:
COMPOSITION OF WET MIX
Per Cent
Hydrated lime 45
Cement 14
Kieselguhr 6
Sodium hydroxide 1
Water 33 (approx.)
AFTER DRYING
Moisture content 8 (approx.)
AFTER SPRAYING
Moisture content 13 (approx.)
Sodium permanganate content 3 (approx.)
Within limits, the method of manufacture is more important than the
composition or other variables, and has been the subject of a great
deal of research work even on apparently minor details. The process
finally adopted consists essentially in making a plastic mass of lime,
cement, kieselguhr, caustic soda, and water, spreading in slabs on
wire-bottomed trays, allowing to set for 2 or 3 days under carefully
controlled conditions, drying, grinding, and screening to 8-14 mesh,
and finally spraying with a strong solution of sodium permanganate with
a specially designed spray nozzle. The spraying process is a recent
development, most of the soda-lime having been made by putting the
sodium permanganate into the original wet mix. Many difficulties had to
be overcome in developing the spraying process, but it eventually gave
a better final product, and resulted in a large saving of permanganate
which was formerly lost during drying, in fines, etc.
FUNCTION OF DIFFERENT COMPONENTS
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