Smoke screens have been frequently used by the Navy and by Merchantmen;
a common method of escape was to shut off the air from the fire with
consequent incomplete combustion of the fuel, thus causing a cloud of
dense black smoke. This is often mentioned in the blockade runners of
the days in the Civil War, where wood, high in pitch and rosin, was
freely introduced into the furnaces, in order that they might escape
under cover of this smoke.
Early in the present war it was found that black smoke had a low
obscuring power, showed frequent rents or holes and were difficult
to standardize. Their production also caused a considerable loss in
the speed of the vessel. They therefore fell into disuse except for
emergency purposes and today the standard smoke for screening purposes
of all kinds is, without exception, white.[33]
[Footnote 33: While it is a well known fact that black smoke is not as
efficient as white smoke for screening purposes, the reason for this
fact is not clear.]
PROPERTIES OF SMOKE CLOUD
The properties most desired in a screening smoke, apart from low cost,
are: (_a_) _Maximum screening power_, which refers to the question of
density, i.e., a relatively thin layer must completely obscure any
object behind it, and (_b_) _Stability_, which implies, among other
things, a low rate of settling or dissipation. There is little reason
to doubt that, within limits, the smaller the particles of a smoke
cloud, the more completely will the smoke possess these qualities.
The screening power of a smoke cloud depends very largely upon the
scattering of the light coming through it, and by analogy with those
peculiar solutions which we call colloidal, we should expect the
scattering to increase as the degree of subdivision increases, within
limits. The rate of settling is unquestionably an inverse function
of the size of the particles. The chief aim, therefore, in smoke
production is to attain as high a degree of subdivision as possible.
Methods may be classified as good or bad, in so far as they satisfy or
fail to satisfy this criterion.
RAW MATERIALS FOR SMOKE CLOUDS
It is obvious that only gases or substances capable of being brought
into the vapor state or into a very fine state of subdivision can be
used for producing smoke clouds. The reaction product, of which the
smoke particles consist, should preferably be:
(_a_) _Solid._ Otherwise the particles will tend to grow in size by
condensation of the liquid particles present in the cloud.
(_b_) _Non-volatile._ If volatile, the particles will disappear by
evaporation as the cloud is diluted by air currents. Larger particles
will also form at the expense of the smaller ones.
(_c_) _Non-deliquescent._ If the particles are deliquescent, they will
tend to grow by condensation of water vapor upon them.
(_d_) _Stable_ towards the usual components of the atmosphere,
especially moisture.
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