When a sample of smoke is viewed in the ultra-microscope, it appears
like the starry heavens, except that the stars are dancing violently
about. At first little distinction is made between the particles, as
there seems to be no order in their motion, but soon it becomes evident
that the brighter particles are more sluggish than the dim ones. This
is due to the greater mass of the bright particles, for they are
larger. The particles are all moving slowly away from the source of
light and eventually diffuse to the walls of the cell.
When the electric field is turned on, about one-third of the particles
immediately migrate, about equally in both directions, to the two
electrodes. If the field is reversed, the direction of migration
is reversed and if the commutator is used the particles oscillate
regularly. Sometimes the particles may be seen to combine and become
neutral, in which case oscillation ceases.
CONCENTRATION OF SMOKE
In measuring the concentration of smokes, the following terms are
useful:
=Density.= The density of a smoke is defined as the reciprocal of the
thickness of the smoke layer in feet necessary to obscure a given
filament. Thus six inches of a smoke of density 2.0 is required to
obscure an electric light filament, whereas one requiring four feet
would have a density of 4. Another way to show the significance of this
definition is to point out that if a definite weight of a stable smoke
is diluted with air after it is formed, the product of the volume by
the density always remains constant. Any marked variation in this rule
may be taken as evidence that the particles of smoke are undergoing a
change, in most cases due to evaporation.
=Total Obscuring Power.= The volume of smoke produced per unit weight
of material used is the second factor in determining the value of a
smoke. The product of this volume per unit weight by the density of the
smoke is the real measure of effectiveness, and is called the total
obscuring power (T. O. P.) of the smoke. If the volume is expressed in
cubic feet per pound and the density in reciprocal feet, the unit of T.
O. P. is square feet per pound. That is, it expresses the square feet
of a smoke wall, thick enough to completely obscure a light filament
behind it, which could be produced from a pound of the reacting
substances. The total obscuring power of some typical smokes are as
follows:
Phosphorus 4600
NH₄Cl(NH₃ + HCl) 2500
SnCl₄ + NH₃ + H₂O 1590
Berger Mixture 1250
SnCl₄ + NH₃ 900
SO₂ + NH₃ 375
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account