An analogous result was obtained by the use of poison gases, such
as chloropicrin, in a smoke cloud produced from silicon or stannic
chloride. Here, however, the toxic material was a real gas, and so the
real result attained consisted in forcing the men to wear their masks
in all kinds of clouds. The true toxic smoke went further in that the
ordinary mask offered little protection and thus compelled the warring
nations to develop a special type of smoke filter.
These smoke clouds consist of very small particles, which may be
considered as a _dispersed_ phase, distributed in the air, which we may
call the _dispersing medium_. The dispersed phase may be produced by
_mechanical_, _thermal_, or _chemical_ methods.
_Mechanical dispersion_ consists in the tearing apart of the material
into a fine state of subdivision. It may be called a hammer and anvil
action. The more powerful the mechanical force, the smaller the
resulting particles. This may be accomplished by the use of a high
explosive, such as the Germans used in the case of diphenylchloroarsine.
The production of smoke by _thermal dispersion_ depends essentially
upon the fact that when a substance of sufficiently low vapor pressure
is volatilized, and the vapors are passed into the air, they
recondense on the nuclei of the air to form a smoke. Vaporization from
an open container, permitting the vapors to pass directly to the air
without being quickly carried away from the surface of evaporation,
produces smoke having larger particles, because each particle formed
remains for an appreciable period of time in contact with air saturated
with vapor, and hence grows very rapidly.
The easiest way to produce small smoke particles is to mix the toxic
material directly with some fuel which will produce a large amount of
heat and gas upon burning. When this mixture is enclosed in a container
having a small orifice, upon burning, the toxic vapor and gas will pass
through this orifice at high velocity; it has been demonstrated by Lord
Rayleigh that the size of the particles depends upon the velocity of
emission of the gas from a given orifice.
The product of _chemical combination_ may include a super-saturated
vapor, which condenses into small particles.
_Explosive dispersion_ is really a combination of _mechanical
dispersion_ followed by _thermal dispersion_.
PENETRATION
The fundamental idea underlying all the work on toxic smokes is to
obtain a smoke that has marked penetrating power. Screening power is
not important here. In addition to penetration, a smoke should be
highly toxic and have a slow rate of settling.
Public-domain text, read in full here on John Shaqi.
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