“The remaining solution percolates from the cathode compartment through
the asbestos diaphragm into the anode compartment and flows from the
end of the cell, containing from 8 to 12 per cent caustic soda, admixed
with 14 to 16 per cent salt, into an open trough and into a pipe in the
trench and through this pipe by gravity to the weak caustic storage
tanks located near the caustic evaporator building.
[Illustration: FIG. 22.—Nelson Electrolytic Cell, showing the Interior
Arrangement of the Cell.]
“The gas piping from the individual cell units to and including the
drying equipment is of chemical stoneware. The piping is so designed
that the gas can be drawn from the cells through the drying equipment
at as near atmospheric pressure as possible in order that the gas can
be kept nearly free of air. When operating, the suction at the pump was
kept at ¹/₂₀ inch or less. The quality of the gas was maintained at a
purity of 98.5 to 99 per cent. The coolers used were very effective,
the gas being cooled to within one degree of the temperature of the
cooling water, no refrigeration being necessary. The drying apparatus
consisted of a stoneware tower of special design containing a large
number of plates, and thus giving a very large acid exposure. There
was practically no loss of vacuum through the drying tower and cooler.
The gas pumping equipment consisted of two hydroturbine pumps using
sulfuric acid as the compressing medium. The acid was cooled by
circulation through a double pipe cooler similar to those used in
refrigerating work. The gas was delivered under about five pounds
pressure into large receiving tanks located just outside the pump
rooms, and from these tanks into steel pipe mains which conducted the
gas to the chemical plant.”
The purity of the gas was such that it was not found necessary to
liquefy it for the preparation of phosgene.
PROPERTIES
Chlorine, at ordinary atmospheric pressure and temperature, is a
greenish yellow gas (giving rise to its name), which has a very
irritating effect upon the membranes of the nose and throat. As
mentioned above, at a pressure of 16.5 atmospheres at 18° C., chlorine
is condensed to a liquid. If the gas is first cooled to 0°, the
pressure required for condensation is decreased to 3.7 atmospheres.
This yellow liquid has a boiling point of -33.6° C. at the ordinary
pressure. If very strongly cooled, chlorine will form a pale yellow
solid (at -102° C.). Chlorine is 2.5 times as heavy as air, one liter
weighing 3.22 grams. 215 volumes of chlorine gas will dissolve in 100
volumes of water at 20°. It is very slightly soluble in hot water or in
a concentrated solution of salt.
Chlorine is a very reactive substance and is found in combination in a
large number of compounds. Among the many reactions which have proved
important from the standpoint of chemical warfare, the following may be
mentioned:
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