Filters, containing solid materials capable of absorbing free chlorine,
have also been used for removing the excess of the germicidal reagent.
Iron borings and aluminium were used experimentally by Thresh[11] but
the process was not commercially developed. The "De Chlor" filter, in
which carbon is the active substance, has been installed at several
water works in England (Reading, Exeter, Aldershot) with apparently
successful results. The Reading experimental installation, described by
Walker,[12] consisted of a steel drum, 8 feet 3 inches in width, the top
and bottom being domed. In the upper portion, 10 feet 9 inches in depth,
provision was made for thorough admixture of the bleach solution and
water and a subsequent storage of thirty minutes. The lower section of
the filter was divided into three compartments, the first and last of
which contained graded silica; the middle compartment was filled with a
layer (20 inches deep) of specially prepared granulated charcoal or
carbon.
The filter was operated under pressure and passed an average of 192,000
Imp. gallons per day, the rate being 32,000 Imp. gallons per square yard
per day.
Water from the pre-filters (polarite and sand) was treated with bleach
to give a concentration of 1 p.p.m. of available chlorine and passed
through the De Chlor filter. The average bacteriological results
obtained during the first six months operation were as follows:
Bacteria Per c.cm. B. coli Index
Gelatine 3 Days at 20° C. Per 100 c.cms.
Raw river water 6,775 600
Water from pre-filters 579 119
Water from De Chlor filter 33 Nil
Free chlorine could not be detected by chemical tests in the filtered
water which was also free from abnormal tastes and odours. It is stated
that the carbon has to be removed and revivified periodically. The
filter was washed about once per week, the wash water being only
one-tenth of one per cent.
The experimental filter was operated for nearly two years before being
removed to permit the erection of larger units having a total capacity
of one million Imp. gallons per day.
BIBLIOGRAPHY
[1] Hooker. Chloride of Lime in Sanitation, New York, 1913.
[2] Griffen and Hedallen. J. Soc. Chem. Ind., 1915, =34=, 530.
[3] Hale. Proc. N. J. San. Assoc., 1914.
[4] Adams. J. Amer. Pub. Health Assoc., 1916, =6=, 867.
[5] Ellms and Hauser. J. Ind. and Eng. Chem., 1913, =5=, 915 and 1030;
_ibid._, 1914, =6=, 553.
[6] Wallis. Ind. Jour. Med. Res., 1917, =4=, 797.
[7] Le Roy. Comptes rend., 1916, =163=, 226.
[8] Winkler. Zeit. angew. Chem., 1915, =28=, 22.
[9]: Rideal, E. K. and Evans. Analyst, 1913, =38=, 353.
[10] J. Amer. Pub. Health Assoc. 1915, =5=, 921.
[11] Thresh. Internat. Congress Appl. Chem., 1908.
[12] Walker. Jour. Roy. Inst. Pub. Health, Jan., 1911.
CHAPTER VII
LIQUID CHLORINE
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