The use of liquefied chlorine for the disinfection of water was first
proposed by Lieutenant Nesfield[1] of the Indian Medical Service. He
stated that: "It occurred to me that chlorine gas might be found
satisfactory ... if suitable means could be found for using it.... The
next important question was how to render the gas portable. This might
be accomplished in two ways: By liquefying it, and storing it in
lead-lined iron vessels, having a jet with a very fine capillary canal,
and fitted with a tap or a screw cap. The tap is turned on, and the
cylinder placed in the amount of water required. The chlorine bubbles
out, and in ten to fifteen minutes the water is absolutely safe, and has
only to be rendered tasteless by the addition of sodium sulphite made
into a cake or tablet.... The cylinders could, of course, be refilled.
This method would be of use on a large scale, as for service water
carts."
The first _practical_ demonstration of the possibilities of this method
was made by Major Darnall[2] of the Medical Corps, United States Army,
in 1910. Chlorine was taken from steel cylinders and passed through
automatic reducing valves which provided a uniform flow of gas for the
water requiring treatment. A uniform flow of water was maintained
through the mixing pipe and so secured a uniform dosage. This apparatus
might be considered as the forerunner of the various commercial types of
machines that were developed later and which are being so extensively
used at the present time.
A working model, having a capacity of 500 gallons per hour, was erected
at Fort Myer, Va., and was operated on water that had been treated with
alum but had received no further purification. Despite the presence of
the flocculated organic matter, satisfactory purification was obtained
with 0.5 to 1.0 p.p.m. of available chlorine and no taste or odour was
imparted to the supply.
From the results obtained at Fort Myer, and Washington, D.C., Darnall
concluded that "In general, it may be said that with an average
unfiltered river water such as that of the Potomac, about one-half of
one part (by weight) of chlorine gas per million of water will be
required. For clear lake waters three-tenths to four-tenths of a part
per million will be sufficient."
A Board of Officers of the War Department examined the results and
reported (June, 1911) "That the apparatus is as efficient as
purification by ozone or hypochlorite and is more reliable in operation
than either.... That it could be installed at a very low cost and that
the cost of operation would be very slight."
In June, 1912, Ornstein experimented with chlorine gas, obtained from
the liquefied gas in cylinders, for sewage and water disinfection but
his method differed from Darnall's in first dissolving the gas in water
and feeding the solution to the liquid to be treated.
Public-domain text, read in full here on John Shaqi.
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