The operation of liquid chlorine machines is exceedingly simple. After
the cylinders have been connected, the cylinder valves are opened and
the joints tested for leakage by holding a swab of absorbent cotton
saturated with strong ammonia under them; a leakage is indicated by the
appearance of white fumes of ammonium chloride. The control valve is
then slightly opened and the auxiliary cylinder valves partially opened;
whilst the pressure in the apparatus is slowly increasing the remainder
of the joints are tested and if found to be tight, the cylinder valves
are fully opened and the control valve opened to the desired amount. In
the solution feed types the water required as solvent is turned on
before the control valve is opened. Once the apparatus is working, no
further attention is required, except for the regulation of the dosage
in the manual control types, until the cylinders are replaced. When the
stock of gas in the cylinders is almost depleted the pressure falls but
it is always preferable to determine the stock by standing the cylinders
on a platform scale and weighing at regular intervals. This also
provides a check on the apparatus and can be utilised to check the
operators.
The accumulation of substances that impede the flow of gas is usually
slow and is indicated by a gradual increase in the back pressure. The
orifice is calibrated at 25 pounds back pressure and any deviation from
this figure will show a discrepancy between the actual weight of
chlorine evaporated and the amount calculated from the scale reading.
Liquid chlorine is usually sent out by the manufacturers in steel
cylinders which contain about 1.1 cubic feet of liquid or approximately
100 pounds (1 cu. ft. = 89.75 pounds).[A]
[A] An effort is now being made to standardise cylinders of 150 lbs.
capacity.
For small installations only one cylinder is necessary but it is always
preferable to connect more than one. When the flow of gas is rapid the
temperature of the liquid chlorine falls and reduces the pressure. The
effect of the fall in temperature, due to the latent heat of
evaporation, can be partially overcome by using a larger number of
cylinders; in addition a source of external heat should be provided that
will maintain the temperature of the cylinders at a minimum of 80° F.
This is a "sine qua non" for successful operation. The effect of the
temperature upon the pressure in the cylinders is shown in Diagram VII.
[Illustration: DIAGRAM VII
CHLORINE GAS PRESSURES AT VARIOUS TEMPERATURES]
In practice it is found impossible to utilise all the gas contained in
the containers; when the cylinders are almost empty the pressure
necessary for the operation of the regulating device cannot be obtained
and full cylinders must be attached. When sufficient heat is provided
the weight of chlorine in the cylinder can be reduced to 1 - 1-1/2
pounds before the tank pressure becomes too low.
Public-domain text, read in full here on John Shaqi.
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