Chronicles of Pharmacy, Vol. 1 (of 2)Wootton, A. C.
History
Chronicles of Pharmacy, Vol. 1 (of 2)
Wootton, A. C.
Pharmacy -- History
Meanwhile the nature of the earth with which the sulphuric acid was
combined remained unknown to chemists. Stahl worked at the problem and
came to the conclusion that it was lime. The younger Geoffroy, a famous
pharmacist of Paris, ascertained (1728) that the earth of alum was
identical with that of argillaceous earth and Alumina was for some time
called Argile. Marggraf observed that he could not get alum crystals
from a combination of argile and sulphuric acid, but noting that in
the old factories it had been the custom to add putrid urine to the
solution, for which carbonate of potash was subsequently substituted,
went so far as to make the salt, but did not appreciate that it was
actually a double salt. The name alumina which the earth now bears
was given to it by Morveau. It was Vauquelin (another pharmacist) who
clearly proved the composition of alum, and Lavoisier first suggested
that alumina was the oxide of a metal. Sir Humphry Davy agreed with
this view but failed to isolate the metal. Oersted was the first to
actually extract aluminium from the oxide, but his process was an
impracticable one, but in 1828 Woehler, and in 1858 Deville, found
means of producing the metal in sufficient abundance to make it a
valuable article of industry.
AMMONIA.
The chemical history of ammonia commences in Egypt with Sal
Ammoniac. This is mentioned by Pliny under the name of Hammoniacus
sal. Dioscorides also alludes to it; but in neither case does the
description given fit in satisfactorily with the product known to us.
Dioscorides, for instance, states that sal ammoniac is particularly
prized if it can lie easily split up into rectangular fragments. It
has been conjectured that what was called sal ammoniac by the ancient
writers was, at least sometimes, rock salt.
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