Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
It may also be seen from the above experiments, that a given quantity
of air can only unite with, and at the same time saturate, a certain
quantity of the inflammable substance: this is evident from the ninth
paragraph, letter b. But whether the phlogiston which was lost by the
substances was still present in the air left behind in the bottle,
or whether the air which was lost had united and fixed itself with
the materials such as liver of sulphur, oils, &c., are questions of
importance.
From the first view, it would necessarily follow that the inflammable
substance possessed the property of depriving the air of part of its
elasticity, and that in consequence of this it becomes more closely
compressed by the external air. In order now to help myself out of
these uncertainties, I formed the opinion that any such air must
be specifically heavier than ordinary air, both on account of its
containing phlogiston and also of its greater condensation. But how
perplexed was I when I saw that a very thin flask which was filled with
this air, and most accurately weighed, not only did not counterpoise
an equal quantity of ordinary air, but was even somewhat lighter. I
then thought that the latter view might be admissible; but in that case
it would necessarily follow also that the lost air could be separated
again from the materials employed. None of the experiments cited seemed
to me capable of showing this more clearly than that according to the
tenth paragraph, because this residuum, as already mentioned, consists
of vitriolated tartar and alkali. In order therefore to see whether the
lost air had been converted into fixed air, I tried whether the latter
shewed itself when some of the caustic ley was poured into lime-water;
but in vain--no precipitation took place. Indeed, I tried in several
ways to obtain the lost air from this alkaline mixture, but as the
results were similar to the foregoing, in order to avoid prolixity I
shall not cite these experiments. Thus much I see from the experiments
mentioned, that the air consists of two fluids, differing from each
other, the one of which does not manifest in the least the property
of attracting phlogiston, while the other, which composes between the
third and the fourth part of the whole mass of the air, is peculiarly
disposed to such attraction. But where this latter kind of air has gone
to after it has united with the inflammable substance, is a question
which must be decided by further experiments, and not by conjectures.
FOOTNOTES:
[Footnote 18: Translated from _Treatise on Air and Fire_ (1777).]
XVII
ANTOINE LAURENT LAVOISIER
1743-1794
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