Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
The alkali in the mixture, uniting with the acid, separates it from
the magnesia; which, not being of itself soluble in water, must
consequently appear immediately under a solid form. But the powder
which thus appears is not entirely magnesia; part of it is the neutral
salt formed from the union of the acid and alkali. This neutral salt
is found, upon examination, to agree in all respects with vitriolated
tartar, and requires a large quantity of hot water to dissolve it. As
much of it is therefore dissolved as the water can take up; the rest
is dispersed through the mixture, in the form of a powder. Hence the
necessity of washing the magnesia with so much trouble; for the first
effusion of hot water is intended to dissolve the whole of the salt,
and the subsequent additions of cold water to wash away this solution.
The caution given, of boiling the mixture, is not unnecessary: if it
be neglected, the whole of the magnesia is not accurately separated at
once; and, by allowing it to rest for some time, that powder concretes
into minute grains, which, when viewed with the microscope, appear to
be assemblages of needles diverging from a point. This happens more
especially when the solutions of the Epsom salt, and of the alkali,
are diluted with too much water before they are mixed together. Thus,
if a dram of Epsom salt, and of salt of tartar, be dissolved each in
four ounces of water, and be mixed, and then allowed to rest three or
four days, the whole of the magnesia will be formed into these grains.
Or, if we filtrate the mixture soon after it is made, and heat the
clear liquor which passes through, it will become turbid, and deposit a
magnesia.
An ounce of magnesia was exposed in a crucible, for about an hour, to
such a heat as is sufficient to melt copper. When taken out, it weighed
three drams and one scruple, or had lost 7-12 of its former weight.
I repeated, with the magnesia prepared in this manner, most of those
experiments I had already made upon it before calcination, and the
result was as follows:--
It dissolves in all the acids, and with these composes salts exactly
similar to those described in the first set of experiments: But, what
is particularly to be remarked, it is dissolved without any the least
degree of effervescence.
It slowly precipitates the corrosive sublimate of mercury, in the form
of a black powder.
It separates the volatile alkali in salt-ammoniac from the acid, when
it is mixed with a warm solution of that salt. But it does not separate
an acid from a calcareous earth, nor does it introduce the least change
upon lime-water.
Lastly, when a dram of it is digested with an ounce of water in a
bottle for some hours, it does not make any the least change in the
water. The magnesia, when dried, is found to have gained ten grains;
but it neither effervesces with acids, nor does it sensibly affect
lime-water.
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