Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
_Joseph Priestley, born in Yorkshire, England, March 13, 1733, was
a Unitarian minister. In 1774 he discovered oxygen, which he called
“dephlogisticated air.” Because of his liberal political ideas he was
persecuted by his countrymen, and in 1794 emigrated to Northumberland,
Pennsylvania, where he lived until his death, February 6, 1804._
THE DISCOVERY OF OXYGEN[15]
Presently, after my return from abroad, I went to work upon the
_mercurius calcinatus_, which I had procured from Mr. Cadet; and,
with a very moderate degree of heat, I got from about one-fourth of
an ounce of it, an ounce-measure of air, which I observed to be not
readily imbibed, either by the substance itself from which it had
been expelled (for I suffered them to continue a long time together
before I transferred the air to any other place) or by water, in which
I suffered this air to stand a considerable time before I made any
experiment upon it.
In this air, as I had expected, a candle burned with a vivid flame; but
what I observed new at this time (November 19), and which surprised me
no less than the fact I had discovered before, was, that, whereas a
few moments agitation in water will deprive the modified nitrous air
of its property of admitting a candle to burn in it; yet, after more
than ten times as much agitation as would be sufficient to produce this
alteration in the nitrous air, no sensible change was produced in this.
A candle still burned in it with a strong flame; and it did not, in
the least, diminish common air, which I have observed that nitrous air,
in this state, in some measure does.
But I was much more surprised, when, after two days, in which this air
had continued in contact with water (by which it was diminished about
one-twentieth of its bulk) I agitated it violently in water about five
minutes, and found that a candle still burned in it as well as in
common air. The same degree of agitation would have made phlogisticated
nitrous air fit for respiration indeed, but it would certainly have
extinguished a candle.
These facts fully convinced me, that there must be a very material
difference between the constitution of air from _mercurius
calcinatus_, and that of phlogisticated nitrous air, notwithstanding
their resemblance in some particulars. But though I did not doubt that
the air from _mercurius calcinatus_ was fit for respiration, after
being agitated in water, as every kind of air without exception, on
which I have tried the experiment, had been, I still did not suspect
that it was respirable in the first instance; so far was I from having
any idea of this air being, what it really was, much superior, in this
respect, to the air of the atmosphere.
Public-domain text, read in full here on John Shaqi.
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