It is quite possible that the very reason why it existed in such a
rarefied or gaseous condition was its excessive temperature, and that
condensation only began to take place when the mass began to cool down.
It seems far more probable that this should have been the case than
that the mass existed in so rarefied a condition without temperature.
For why should the particles have existed in this separated form when
devoid of the repulsive energy of heat, seeing that in virtue of
gravitation they had such a tendency to approach to one another? But
if the mass was originally in a heated condition, then in condensing
it would have to part not only with the heat generated in condensing,
but also with the heat which it originally possessed, a quantity
which would no doubt much exceed that produced by condensation. To
illustrate this principle, let us suppose a pound of air, for example,
to be placed in a cylinder and heat applied to it. If the piston be so
fixed that it cannot move, 234·5 foot-pounds of heat will raise the
temperature of the air 1° C. But if the piston be allowed to rise as
the heat is applied, then it will require 330·2 foot-pounds of heat to
raise the temperature 1° C. It requires 95·7 foot-pounds more heat in
the latter case than in the former. The same amount of energy, viz.,
234·5 foot-pounds, in both cases goes to produce temperature; but in
the latter case, where the piston is allowed to move, 95·7 foot-pounds
of additional heat are consumed in the mechanical work of raising the
piston. Suppose, now, that the air is allowed to cool under the same
conditions: in the one case 234·5 foot-pounds of heat will be given
out while the temperature of the air sinks 1° C.; in the other case,
where the piston is allowed to descend, 330·2 foot-pounds will be given
out while the temperature sinks 1° C. In the former case, the air in
cooling has simply to part with the energy which it possesses in
the form of temperature; but in the latter case it has, in addition
to this, to part with the energy bestowed upon its molecules by the
descending piston. While the temperature of the gas is sinking 1°,
95·7 foot-pounds of energy in the form of heat are being imparted to
it by the descending piston; and these have to be got rid of before
the temperature is lowered by 1°. Consequently 234·5 foot-pounds of
the heat given out previously existed in the air under the form of
temperature, and the remaining 95·7 foot-pounds given out were imparted
to the air by the descending piston while the gas was losing its
temperature. 234·5 foot-pounds represent the energy or heat which the
air previously possessed, and 95·7 the energy or heat of condensation.
Public-domain text, read in full here on John Shaqi.
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