It has long been known in photography, that a developer must be of the
nature of a reducing agent, either inorganic or organic, and many
hydroxylic and amidic derivatives of hydrocarbons come under this
category. Thus, pyrogallol, which has already been referred to as a
trihydroxybenzene (p. 146), when dissolved in alkali rapidly absorbs
oxygen--it is a strong reducing agent, and is thus of value as a
developer. But although pyrogallol is a benzene derivative, and could if
necessary be prepared synthetically, it can hardly be claimed as a tar
product, as it is generally made from gallic acid. Now hydroquinone when
dissolved in alkali also acts as a reducing agent, and in this we have the
first application of a true coal-tar product as a photographic developer.
Its use for this purpose was suggested by Captain Abney in 1880, and it
was found to possess certain advantages which caused it to become
generally adopted.
As soon as a practical use is found for a chemical product its manufacture
follows as a matter of course. In the case of hydroquinone, the original
source, quinic acid, was obviously out of question, for economical
reasons. In 1877, however, Nietzki worked out a very good process for the
preparation of quinone from aniline by oxidation with sulphuric acid and
bichromate of soda in the cold. This placed the production of quinone on a
manufacturing basis, so that when a demand for hydroquinone sprung up, the
wants of the photographer were met by the technologist. Eikonogen is
another organic reducing agent, discovered by the writer in 1880, and
introduced as a developer by Dr. Andresen in 1889. It is an
amido-derivative of a sulpho-acid of beta-naphthol, so that naphthalene is
the generating hydrocarbon of this substance.
Public-domain text, read in full here on John Shaqi.
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