When you shake the oil with the water, the oil breaks up into tiny
droplets. These droplets are so small that they reflect the light that
strikes them and so look white, or pale yellow. This milky mixture is
called an _emulsion_. Milk is an emulsion; there are tiny droplets of
butter fat and other substances scattered all through the milk. The
butter fat is _not_ dissolved in the rest of the milk, and the oil is
_not_ dissolved in the water. But the droplets may be so small that an
emulsion acts almost exactly like a solution.
[Illustration: FIG. 146. Will heating the water make more salt
dissolve?]
But when you shake or stir salt or sugar in water, the particles
divide up into smaller and smaller pieces, until probably each piece
is just a single molecule of the salt or sugar. And these molecules
get into the spaces between the water molecules and bounce around
among them. They therefore act like the water and let the light
through. This is a solution. The salt or sugar is _dissolved_ in the
water. Any liquid mixture which remains clear is a solution, no matter
what the color. Most red ink, most blueing, clear coffee, tea, and
ocean water are solutions. If a liquid is _clear_, no matter what
the color, you can be sure that whatever things may be in it are
dissolved.
[Illustration: FIG. 147. Will the volume be doubled when the alcohol
and water are poured together?]
EXPERIMENT 82. Pour alcohol into a test tube (square-bottomed
test tubes are best for this experiment), standing the tube
up beside a ruler. When the alcohol is just 1 inch high in the
tube, stop pouring. Put exactly the same amount of water
in another test tube of the same size. When you pour them
together, how many inches high do you think the mixture will
be? Pour the water into the alcohol, shake the mixture a
little, and measure to see how high it comes in the test tube.
Did you notice the warmth when you shook the tube?
If you use denatured alcohol, you are likely to have an
emulsion as a result of the mixing. The _alcohol_ part of the
denatured alcohol dissolves in the water well enough, but the
_denaturing_ substance _in_ the alcohol will not dissolve
in water; so it forms tiny droplets that make the mixture of
alcohol and water cloudy.
The purpose of this experiment is to show that the molecules of water
get into the spaces between the molecules of alcohol. It is as if you
were to add a pail of pebbles to a pail of apples. The pebbles would
fill in between the apples, and the mixture would not nearly fill two
pails.
Public-domain text, read in full here on John Shaqi.
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