Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
Sulphureous acid, as we have already observed, is a permanent gas, and
can be obtained in a liquid form only by condensing it in water. In its
pure state, the sulphureous acid is invisible, and it now appears in the
form of a white smoke, from its combining with the moisture. But the
vapour of sulphuric acid, which you have just seen to rise during the
combustion, is not a gas, but only a vapour, which condenses into liquid
sulphuric acid, by losing its caloric. But it appears from Sir H. Davy’s
experiments, that this formation and condensation of sulphuric acid
requires the presence of water, for which purpose the vapour is received
into cold water, which may afterwards be separated from the acid by
evaporation.
Sulphur has hitherto been considered as a simple substance; but Sir H.
Davy has suspected that it contains a small portion of hydrogen, and
perhaps also of oxygen.
On submitting sulphur to the action of the Voltaic battery, he observed
that the negative wire gave out hydrogen; and the existence of hydrogen
in sulphur was rendered still more probable by his observing that a
small quantity of water was produced during the combustion of sulphur.
EMILY.
And pray of what nature is sulphur when perfectly pure?
MRS. B.
Sulphur has probably never been obtained perfectly free from
combination, so that its radical may possibly possess properties very
different from those of common sulphur. It has been suspected to be of a
metallic nature; but this is mere conjecture.
Before we quit the subject of sulphur, I must tell you that it is
susceptible of combining with a great variety of substances, and
especially with hydrogen, with which you are already acquainted.
Hydrogen gas can dissolve a small portion of it.
EMILY.
What! can a gas dissolve a solid substance?
MRS. B.
Yes; a solid substance may be so minutely divided by heat, as to become
soluble in a gas: and there are several instances of it. But you must
observe, that, in this case, a chemical union or combination of the
sulphur with the hydrogen gas is produced. In order to effect this, the
sulphur must be strongly heated in contact with the gas; the heat
reduces the sulphur to such a state of extreme division, and diffuses it
so thoroughly through the gas, that they combine and incorporate
together. And as a proof that there must be a chemical union between the
sulphur and the gas, it is sufficient to remark that they are not
separated when the sulphur loses the caloric by which it was
volatilized. Besides, it is evident, from the peculiar fetid smell of
this gas, that it is a new compound totally different from either of its
constituents; it is called _sulphuretted hydrogen gas_, and is contained
in great abundance in sulphureous mineral waters.
CAROLINE.
Are not the Harrogate waters of this nature?
MRS. B.
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