Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
No; their attraction for oxygen varies extremely. There are some that
will combine with it only at a very high temperature, or by the
assistance of acids; whilst there are others that oxydate spontaneously
and with great rapidity, even at the lowest temperature; such is in
particular manganese, which scarcely ever exists in the metallic state,
as it immediately absorbs oxygen on being exposed to the air, and
crumbles to an oxyd in the course of a few hours.
EMILY.
Is not that the oxyd from which you extracted the oxygen gas?
MRS. B.
It is: so that, you see, this metal attracts oxygen at a low
temperature, and parts with it when strongly heated.
EMILY.
Is there any other metal that oxydates at the temperature of the
atmosphere?
MRS. B.
They all do, more or less, excepting gold, silver, and platina.
Copper, lead, and iron, oxydate slowly in the air, and cover themselves
with a sort of rust, a process which depends on the gradual conversion
of the surface into an oxyd. This rusty surface preserves the interior
metal from oxydation, as it prevents the air from coming in contact with
it. Strictly speaking, however, the word rust applies only to the oxyd,
which forms on the surface of iron, when exposed to air and moisture,
which oxyd appears to be united with a small portion of carbonic acid.
EMILY.
When metals oxydate from the atmosphere without an elevation of
temperature, some light and heat, I suppose, must be disengaged, though
not in sufficient quantities to be sensible.
MRS. B.
Undoubtedly; and, indeed, it is not surprising that in this case the
light and heat should not be sensible, when you consider how extremely
slow, and, indeed, how imperfectly, most metals oxydate by mere exposure
to the atmosphere. For the quantity of oxygen with which metals are
capable of combining, generally depends upon their temperature; and the
absorption stops at various points of oxydation, according to the degree
to which their temperature is raised.
EMILY.
That seems very natural; for the greater the quantity of caloric
introduced into a metal, the more will its positive electricity be
exalted, and consequently the stronger will be its affinity for oxygen.
MRS. B.
Certainly. When the metal oxygenates with sufficient rapidity for light
and heat to become sensible, combustion actually takes place. But this
happens only at very high temperatures, and the product is nevertheless
an oxyd; for though, as I have just said, metals will combine with
different proportions of oxygen, yet with the exception of only five of
them, they are not susceptible of acidification.
Metals change colour during the different degrees of oxydation which
they undergo. Lead, when heated in contact with the atmosphere, first
becomes grey; if its temperature be then raised, it turns yellow, and a
still stronger heat changes it to red. Iron becomes successively a
green, brown, and white oxyd. Copper changes from brown to blue, and
lastly green.
EMILY.
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