Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
The difference between an oxyd and a compound salt, therefore, is very
obvious: the one consists of a metal and oxygen; the other of an oxyd
and an acid.
MRS. B.
Very well: and you will be careful to remember that the metals are
incapable of entering into this combination with acids, unless they are
previously oxydated; therefore, whenever you bring a metal in contact
with an acid, it will be first oxydated and afterwards dissolved,
provided that there be a sufficient quantity of acid for both
operations.
There are some metals, however, whose solution is more easily
accomplished, by diluting the acid in water; and the metal will, in this
case, be oxydated, not by the acid, but by the water, which it will
decompose. But in proportion as the oxygen of the water oxydates the
surface of the metal, the acid combines with it, washes it off, and
leaves a fresh surface for the oxygen to act upon: then other coats of
oxyd are successively formed, and rapidly dissolved by the acid, which
continues combining with the new-formed surfaces of oxyd till the whole
of the metal is dissolved. During this process the hydrogen gas of the
water is disengaged, and flies off with effervescence.
EMILY.
Was not this the manner in which the sulphuric acid assisted the iron
filings in decomposing water?
MRS. B.
Exactly; and it is thus that several metals, which are incapable alone
of decomposing water, are enabled to do it by the assistance of an acid,
which, by continually washing off the covering of oxyd, as it is formed,
prepares a fresh surface of metal to act upon the water.
CAROLINE.
The acid here seems to act a part not very different from that of a
scrubbing-brush. --But pray would not this be a good method of cleaning
metallic utensils?
MRS. B.
Yes; on some occasions a weak acid, as vinegar, is used for cleaning
copper. Iron plates, too, are freed from the rust on their surface by
diluted muriatic acid, previous to their being covered with tin. You
must remember, however, that in this mode of cleaning metals the acid
should be quickly afterwards wiped off, otherwise it would produce fresh
oxyd.
CAROLINE.
Let us watch the dissolution of the copper in the nitric acid; for I am
very impatient to see the salt that is to result from it. The mixture is
now of a beautiful blue colour; but there is no appearance of the
formation of a salt; it seems to be a tedious operation.
MRS. B.
The crystallisation of the salt requires some length of time to be
completed; if, however, you are so impatient, I can easily show you a
metallic salt already formed.
CAROLINE.
But that would not satisfy my curiosity half so well as one of our own
manufacturing.
MRS. B.
It is one of our own preparing that I mean to show you. When we
decomposed water a few days since, by the oxydation of iron filings
through the assistance of sulphuric acid, in what did the process
consist?
CAROLINE.
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