Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
Besides those which Sir H. Davy has obtained, there are several that
have been recently discovered, whose properties are yet but little
known, as for instance, titanium, which was discovered by the Rev. Mr.
Gregor, in the tin-mines of Cornwall; columbium or tantalium, which has
lately been discovered by Mr. Hatchett; and osmium, iridium, palladium,
and rhodium, all of which Dr. Wollaston and Mr. Tennant found mixed in
minute quantities with crude platina, and the distinct existence of
which they proved by curious and delicate experiments.
CAROLINE.
Arsenic has been mentioned amongst the metals. I had no notion that it
belonged to that class of bodies, for I had never seen it but as a
powder, and never thought of it but as a most deadly poison.
MRS. B.
In its pure metallic state, I believe, it is not so poisonous; but it
has such a great affinity for oxygen, that it absorbs it from the
atmosphere at its natural temperature: you have seen it, therefore, only
in its state of oxyd, when, from its combination with oxygen, it has
acquired its very poisonous properties.
CAROLINE.
Is it possible that oxygen can impart poisonous qualities? That valuable
substance which produces light and fire, and which all bodies in nature
are so eager to obtain?
MRS. B.
Most of the metallic oxyds are poisonous, and derive this property from
their union with oxygen. The white lead, so much used in paint, owes its
pernicious effects to oxygen. In general, oxygen, in a concrete state,
appears to be particularly destructive in its effects on flesh or any
animal matter; and those oxyds are most caustic that have an acrid
burning taste, which proceeds from the metal having but a slight
affinity for oxygen, and therefore easily yielding it to the flesh,
which it corrodes and destroys.
EMILY.
What is the meaning of the word _caustic_, which you have just used?
MRS. B.
It expresses that property which some bodies possess, of disorganizing
and destroying animal matter, by operating a kind of combustion, or at
least a chemical decomposition. You must often have heard of caustic
used to burn warts, or other animal excrescences; most of these bodies
owe their destructive power to the oxygen with which they are combined.
The common caustic, called _lunar caustic_, is a compound formed by the
union of nitric acid and silver; and it is supposed to owe its caustic
qualities to the oxygen contained in the nitric acid.
CAROLINE.
But, pray, are not acids still more caustic than oxyds, as they contain
a greater proportion of oxygen?
MRS. B.
Some of the acids are; but the caustic property of a body depends not
only upon the quantity of oxygen which it contains, but also upon its
slight affinity for that principle, and the consequent facility with
which it yields it.
EMILY.
Is not this destructive property of oxygen accounted for?
MRS. B.
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