Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
You are right. This metal is perfectly fluid at the temperature of one
hundred degrees; at fifty degrees it is solid, but soft and malleable;
at thirty-two degrees it is hard and brittle, and its fracture exhibits
an appearance of confused crystallization. It is scarcely more than half
as heavy as water; its specific gravity being about six when water is
reckoned at ten; so that this metal is actually lighter than any known
fluid, even than ether.
Potassium combines with sulphur and phosphorus, forming sulphurets and
phosphurets; it likewise forms alloys with several metals, and
amalgamates with mercury.
EMILY.
But can a sufficient quantity of potassium be obtained, by means of the
Voltaic battery, to admit of all its properties and relations to other
bodies being satisfactorily ascertained?
MRS. B.
Not easily; but I must not neglect to inform you that a method of
obtaining this metal in considerable quantities has since been
discovered. Two eminent French chemists, Thenard and Gay Lussac,
stimulated by the triumph which Sir H. Davy had obtained, attempted to
separate potassium from its combination with oxygen, by common chemical
means, and without the aid of electricity. They caused red hot potash in
a state of fusion to filter through iron turnings in an iron tube,
heated to whiteness. Their experiment was crowned with the most complete
success; more potassium was obtained by this single operation, that
could have been collected in many weeks by the most diligent use of the
Voltaic battery.
EMILY.
In this experiment, I suppose, the oxygen quitted its combination with
the potassium to unite with the iron turnings?
MRS. B.
Exactly so; and the potassium was thus obtained in its simple state.
From that time it has become a most convenient and powerful instrument
of deoxygenation in chemical experiments. This important improvement,
engrafted on Sir H. Davy’s previous discoveries, served but to add to
his glory, since the facts which he had established, when possessed of
only a few atoms of this curious substance, and the accuracy of his
analytical statements, were all confirmed when an opportunity occurred
of repeating his experiments upon this substance, which can now be
obtained in unlimited quantities.
CAROLINE.
What a satisfaction Sir H. Davy must have felt, when by an effort of
genius he succeeded in bringing to light and actually giving existence,
to these curious bodies, which without him might perhaps have ever
remained concealed from our view!
MRS. B.
The next substance which Sir H. Davy submitted to the influence of the
Voltaic battery was _Soda_, the other fixed alkali, which yielded to the
same powers of decomposition; from this alkali too, a metallic substance
was obtained, very analogous in its properties to that which had been
discovered in potash; Sir H. Davy has called it SODIUM. It is rather
heavier than potassium, though considerably lighter than water; it is
not so easily fusible as potassium.
Public-domain text, read in full here on John Shaqi.
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