Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
The general properties of alkalies are, an acrid burning taste,
a pungent smell, and a caustic action on the skin and flesh.
CAROLINE.
I wonder they should be caustic, Mrs. B., since they contain so little
oxygen.
MRS. B.
Whatever substance has an affinity for any one of the constituents of
animal matter, sufficiently powerful to decompose it, is entitled to the
appellation of caustic. The alkalies, in their pure state, have a very
strong attraction for water, for hydrogen, and for carbon, which, you
know, are the constituent principles of oil, and it is chiefly by
absorbing these substances from animal matter that they effect its
decomposition; for, when diluted with a sufficient quantity of water, or
combined with any oily substance, they lose their causticity.
But, to return to the general properties of alkalies--they change, as we
have already seen, the colour of syrup of violets, and other blue
vegetable infusions, to green; and have, in general, a very great
tendency to unite with acids, although the respective qualities of these
two classes of bodies form a remarkable contrast.
We shall examine the result of the combination of acids and alkalies
more particularly hereafter. It will be sufficient at present to inform
you, that whenever acids are brought in contact with alkalies, or
alkaline earths, they unite with a remarkable eagerness, and form
compounds perfectly different from either of their constituents; these
bodies are called _neutral_ or _compound salts_.
The dry white powder which you see in this phial is pure caustic POTASH;
it is very difficult to preserve it in this state, as it attracts, with
extreme avidity, the moisture from the atmosphere, and if the air were
not perfectly excluded, it would, in a very short time, be actually
melted.
EMILY.
It is then, I suppose, always found in a liquid state?
MRS. B.
No; it exists in nature in a great variety of forms and combinations,
but is never found in its pure separate state; it is combined with
carbonic acid, with which it exists in every part of the vegetable
kingdom, and is most commonly obtained from the ashes of vegetables,
which are the residue that remains after all the other parts have been
volatilised by combustion.
CAROLINE.
But you once said, that after all the volatile parts of a vegetable were
evaporated, the substance that remained was charcoal?
MRS. B.
I am surprised that you should still confound the processes of
volatilisation and combustion. In order to procure charcoal, we
evaporate such parts as can be reduced to vapour by the operation of
heat alone; but when we _burn_ the vegetable, we burn the carbon also,
and convert it into carbonic acid gas.
CAROLINE.
That is true; I hope I shall make no more mistakes in my favourite
theory of combustion.
MRS. B.
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