Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
A very remarkable property of potash is the formation of glass by its
fusion with siliceous earth. You are not yet acquainted with this last
substance, further than its being in the list of simple bodies. It is
sufficient, for the present, that you should know that sand and flint
are chiefly composed of it; alone, it is infusible, but mixed with
potash, it melts when exposed to the heat of a furnace, combines with
the alkali, and runs into glass.
[Footnote *: This defence of the general theory, however
plausible, is liable to some obvious objections. The phenomenon
might perhaps be better accounted for by supposing that a solution
of alkali in water has less capacity for heat than either water or
alkali in their separate state.]
CAROLINE.
Who would ever have supposed that the same substance which converts
transparent oil into such an opake body as soap, should transform that
opake substance, sand, into transparent glass!
MRS. B.
The transparency, or opacity of bodies, does not, I conceive, depend so
much upon their intimate nature, as upon the arrangement of their
particles: we cannot have a more striking instance of this, than is
afforded by the different states of carbon, which, though it commonly
appears in the form of a black opake body, sometimes assumes the most
dazzling transparent form in nature, that of diamond, which, you
recollect, is carbon, and which, in all probability, derives its
beautiful transparency from the peculiar arrangement of its particles
during their crystallisation.
EMILY.
I never should have supposed that the formation of glass was so simple a
process as you describe it.
MRS. B.
It is by no means an easy operation to make perfect glass; for if the
sand, or flint, from which the siliceous earth is obtained, be mixed
with any metallic particles, or other substance, which cannot be
vitrified, the glass will be discoloured, or defaced, by opake specks.
CAROLINE.
That, I suppose, is the reason why objects so often appear irregular and
shapeless through a common glass-window.
MRS. B.
This species of imperfection proceeds, I believe, from another cause. It
is extremely difficult to prevent the lower part of the vessels, in
which the materials of glass are fused, from containing a more dense
vitreous matter than the upper, on account of the heavier ingredients
falling to the bottom. When this happens, it occasions the appearance of
veins or waves in the glass, from the difference of density in its
several parts, which produces an irregular refraction of the rays of
light that pass through it.
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