Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
We have not, I suppose, mixed the acid and the alkali in the exact
proportions that are required for the formation of the salt, otherwise
the mixture would have been almost immediately changed to a solid mass;
but, in order to obtain it in crystals, as you see it in this bottle, it
would be necessary first to dilute it with water, and afterwards to
evaporate the water, during which operation the salt would gradually
crystallise.
CAROLINE.
But of what use is the addition of water, if it is afterwards to be
evaporated?
MRS. B.
When suspended in water, the acid and the alkali are more at liberty to
act on each other, their union is more complete, and the salt assumes
the regular form of crystals during the slow evaporation of its solvent.
Sulphat of soda liquefies by heat, and effloresces in the air.
EMILY.
Pray what is the meaning of the word _effloresces_? I do not recollect
your having mentioned it before.
MRS. B.
A salt is said to effloresce when it loses its water of crystallisation
on being exposed to the atmosphere, and is thus gradually converted into
a dry powder: you may observe that these crystals of sulphat of soda are
far from possessing the transparency which belongs to their crystalline
state; they are covered with a white powder, occasioned by their having
been exposed to the atmosphere, which has deprived their surface of its
lustre, by absorbing its water of crystallisation. Salts are, in
general, either _efflorescent_ or _deliquescent_: this latter property
is precisely the reverse of the former; that is to say, deliquescent
salts absorb water from the atmosphere, and are moistened and gradually
melted by it. Muriat of lime is an instance of great deliquescence.
EMILY.
But are there no salts that have the same degree of attraction for water
as the atmosphere, and that will consequently not be affected by it?
MRS. B.
Yes; there are many such salts, as, for instance, common salt, sulphat
of magnesia, and a variety of others.
_Sulphat of lime_ is very frequently met with in nature, and constitutes
the well-known substance called _gypsum_, or _plaster of Paris_.
_Sulphat of magnesia_, commonly called _Epsom salt_, is another very
bitter medicine, which is obtained from sea-water and from several
springs, or may be prepared by the direct combination of its
ingredients.
We have formerly mentioned _sulphat of alumine_ as constituting the
common _alum_; it is found in nature chiefly in the neighbourhood of
volcanos, and is particularly useful in the arts, from its strong
astringent qualities. It is chiefly employed by dyers and
calico-printers, to fix colours; and is used also in the manufacture of
some kinds of leather.
Sulphuric acid combines also with the metals.
CAROLINE.
One of these combinations, _sulphat of iron_, we are already well
acquainted with.
MRS. B.
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