Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
The next combinations of nitrogen and oxygen form only oxyds of
nitrogen, the first of which is commonly called _nitrous air_; or more
properly _nitric oxyd gas_. This may be obtained from nitric acid, by
exposing the latter to the action of metals, as in dissolving them it
does not yield the whole of its oxygen, but retains a portion of this
principle sufficient to convert it into this peculiar gas, a specimen of
which I have prepared, and preserved within this inverted glass bell.
EMILY.
It is a perfectly invisible elastic fluid.
MRS. B.
Yes; and it may be kept any length of time in this manner over water, as
it is not, like the nitric and nitrous acids, absorbable by it. It is
rather heavier than atmospherical air, and is incapable of supporting
either combustion or respiration. I am going to incline the glass gently
on one side, so as to let some of the gas escape--
EMILY.
How very curious! --It produces orange fumes like the nitrous acid! that
is the more extraordinary, as the gas within the glass is perfectly
invisible.
MRS. B.
It would give me much pleasure if you could make out the reason of this
curious change without requiring any further explanation.
CAROLINE.
It seems, by the colour and smell, as if it were converted into nitrous
acid gas: yet that cannot be, unless it combines with more oxygen; and
how can it obtain oxygen the very instant it escapes from the glass?
EMILY.
From the atmosphere, no doubt. Is it not so, Mrs. B.?
MRS. B.
You have guessed it; as soon as it comes in contact with the atmosphere,
it absorbs from it the additional quantity of oxygen necessary to
convert it into nitrous acid gas. And, if I now remove the bottle
entirely from the water, so as to bring at once the whole of the gas
into contact with the atmosphere, this conversion will appear still more
striking--
EMILY.
Look, Caroline, the whole capacity of the bottle is instantly tinged of
an orange colour!
MRS. B.
Thus, you see, it is the most easy process imaginable to convert
_nitrous oxyd gas_ into _nitrous acid gas_. The property of attracting
oxygen from the atmosphere, without any elevation of temperature, has
occasioned this gaseous oxyd being used as a test for ascertaining the
degree of purity of the atmosphere. I am going to show you how it is
applied to this purpose. --You see this graduated glass tube, which is
closed at one end, (PLATE X. Fig. 2.) --I first fill it with water, and
then introduce a certain measure of nitrous gas, which, not being
absorbable by water, passes through it, and occupies the upper part of
the tube. I must now add rather above two-thirds of oxygen gas, which
will just be sufficient to convert the nitrous oxyd gas into nitrous
acid gas.
CAROLINE.
So it has! --I saw it turn of an orange colour; but it immediately
afterwards disappeared entirely, and the water, you see, has risen, and
almost filled the tube.
MRS. B.
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