Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
Carbonic acid gas is found very abundantly in nature; it is supposed to
form about one thousandth part of the atmosphere, and is constantly
produced by the respiration of animals; it exists in a great variety of
combinations, and is exhaled from many natural decompositions. It is
contained in a state of great purity in certain caves, such as the
_Grotto del Cane_, near Naples.
EMILY.
I recollect having read an account of that grotto, and of the cruel
experiments made on the poor dogs, to gratify the curiosity of
strangers. But I understood that the vapour exhaled by this cave was
called _fixed air_.
MRS. B.
That is the name by which carbonic acid was known before its chemical
composition was discovered. --This gas is more destructive of life than
any other; and if the poor animals that are submitted to its effects are
not plunged into cold water as soon as they become senseless, they do
not recover. It extinguishes flame instantaneously. I have collected
some in this glass, which I will pour over the candle.
CAROLINE.
This is extremely singular--it seems to extinguish it as it were by
enchantment, as the gas is invisible. I never should have imagined that
gas could have been poured like a liquid.
MRS. B.
It can be done with carbonic acid only, as no other gas is sufficiently
heavy to be susceptible of being poured out in the atmospherical air
without mixing with it.
EMILY.
Pray by what means did you obtain this gas?
MRS. B.
I procured it from marble. Carbonic acid gas has so strong an attraction
for all the alkalies and alkaline earths, that these are always found in
nature in the state of carbonats. Combined with lime, this acid forms
chalk, which may be considered as the basis of all kinds of marbles, and
calcareous stones. From these substances carbonic acid is easily
separated, as it adheres so slightly to its combinations, that the
carbonats are all decomposable by any of the other acids. I can easily
show you how I obtained this gas; I poured some diluted sulphuric acid
over pulverised marble in this bottle (the same which we used the other
day to prepare hydrogen gas), and the gas escaped through the tube
connected with it; the operation still continues, as you may easily
perceive--
EMILY.
Yes, it does; there is a great fermentation in the glass vessel. What
singular commotion is excited by the sulphuric acid taking possession of
the lime, and driving out the carbonic acid!
CAROLINE.
But did the carbonic acid exist in a gaseous state in the marble?
MRS. B.
Certainly not; the acid, when in a state of combination, is capable of
existing in a solid form.
CAROLINE.
Whence, then, does it obtain the caloric necessary to convert it into
gas?
MRS. B.
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