Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
If this salt be mixed, and merely rubbed together with sulphur,
phosphorus, charcoal, or indeed any other combustible, it explodes
strongly.
[Footnote *: According to Sir H. Davy’s new views, just explained,
oxy-muriat of potash is a compound of chlorine with oxyd of
potassium.]
CAROLINE.
Like gun-powder, I suppose, it is suddenly converted into elastic
fluids?
MRS. B.
Yes; but with this remarkable difference, that no increase of
temperature, any further than is produced by gentle friction, is
required in this instance. Can you tell me what gases are generated by
the detonation of this salt with charcoal?
EMILY.
Let me consider . . . . . The oxy-muriatic acid parts with its excess of
oxygen to the charcoal, by which means it is converted into muriatic
acid gas; whilst the charcoal, being burnt by the oxygen, is changed to
carbonic acid gas. --What becomes of the potash I cannot tell.
MRS. B.
That is a fixed product which remains in the vessel.
CAROLINE.
But since the potash does not enter into the new combinations, I do not
understand of what use it is in this operation. Would not the
oxy-muriatic acid and the charcoal produce the same effect without it?
MRS. B.
No; because there would not be that very great concentration of oxygen
which the combination with the potash produces, as I have just
explained.
I mean to show you this experiment, but I would advise you not to repeat
it alone; for if care be not taken to mix only very small quantities at
a time, the detonation will be extremely violent, and may be attended
with dangerous effects. You see I mix an exceedingly small quantity of
the salt with a little powdered charcoal, in this Wedgwood mortar, and
rub them together with the pestle--
CAROLINE.
Heavens! How can such a loud explosion be produced by so small a
quantity of matter?
MRS. B.
You must consider that an extremely small quantity of solid substance
may produce a very great volume of gases; and it is the sudden evolution
of these which occasions the sound.
EMILY.
Would not oxy-muriat of potash make stronger gunpowder than nitrat of
potash?
MRS. B.
Yes; but the preparation, as well as the use of this salt, is attended
with so much danger, that it is never employed for that purpose.
CAROLINE.
There is no cause to regret it, I think; for the common gunpowder is
quite sufficiently destructive.
MRS. B.
I can show you a very curious experiment with this salt; but it must
again be on condition that you will never attempt to repeat it by
yourselves. I throw a small piece of phosphorus into this glass of
water; then a little oxy-muriat of potash; and, lastly, I pour in (by
means of this funnel, so as to bring it in contact with the two other
ingredients at the bottom of the glass) a small quantity of sulphuric
acid--
CAROLINE.
This is, indeed, a beautiful experiment! The phosphorus takes fire and
burns from the bottom of the water.
EMILY.
Public-domain text, read in full here on John Shaqi.
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