Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
I know that in painting, the lakes are reckoned far less durable colours
than the ochres; but what is the reason of it?
MRS. B.
The change which takes place in vegetable colours is owing chiefly to
the oxygen of the atmosphere slowly burning their hydrogen, and leaving,
in some measure, the blackness of the carbon exposed. Such change cannot
take place in ochre, which is altogether a mineral substance.
Vegetable colours have a stronger affinity for animal than for vegetable
substances, and this is supposed to be owing to a small quantity of
nitrogen which they contain. Thus, silk and worsted will take a much
finer vegetable dye than linen and cotton.
CAROLINE.
Dying, then, is quite a chemical process?
MRS. B.
Undoubtedly. The condition required to form a good dye is, that the
colouring matter should be precipitated, or fixed, on the substance to
be dyed, and should form a compound not soluble in the liquids to which
it will probably be exposed. Thus, for instance, printed or dyed linens
or cottons must be able to resist the action of soap and water, to which
they must necessarily be subject in washing; and woollens and silks
should withstand the action of grease and acids, to which they may
accidentally be exposed.
CAROLINE.
But if linen and cotton have not a sufficient affinity for colouring
matter, how are they made to resist the action of washing, which they
always do when they are well printed?
MRS. B.
When the substance to be dyed has either no affinity for the colouring
matter, or not sufficient power to retain it, the combination is
effected, or strengthened, by the intervention of a third substance,
called a _mordant_, or basis. The mordant must have a strong affinity
both for the colouring matter and the substance to be dyed, by which
means it causes them to combine and adhere together.
CAROLINE.
And what are the substances that perform the office of thus reconciling
the two adverse parties?
MRS. B.
The most common mordant is sulphat of alumine, or alum. Oxyds of tin and
iron, in the state of compound salts, are likewise used for that
purpose.
_Tannin_ is another vegetable ingredient of great importance in the
arts. It is obtained chiefly from the bark of trees; but it is found
also in nut-galls, and in some other vegetables.
EMILY.
Is that the substance commonly called _tan_, which is used in
hot-houses?
MRS. B.
Tan is the prepared bark in which the peculiar substance, tannin, is
contained. But the use of tan in hot-houses is of much less importance
than in the operation of _tanning_, by which skin is converted into
leather.
EMILY.
Pray, how is this operation performed?
MRS. B.
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