Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
It cannot properly be called ice, since ice implies a degree of cold, at
least equal to the freezing point. Yet as water, in combining with lime,
gives out more heat than in freezing, it must be in a state of still
greater solidity in the lime, than it is in the form of ice; and you may
have observed that it does not moisten or liquefy the lime in the
smallest degree.
EMILY.
But, Mrs. B., the smoke that rises is white; if it was only pure caloric
which escaped, we might feel, but could not see it.
MRS. B.
This white vapour is formed by some of the particles of lime, in a state
of fine dust, which are carried off by the caloric.
EMILY.
In all changes of state, then, a body either absorbs or disengages
latent heat?
MRS. B.
You cannot exactly say _absorbs latent heat_, as the heat becomes latent
only on being confined in the body; but you may say, generally, that
bodies, in passing from a solid to a liquid form, or from the liquid
state to that of vapour, absorb heat; and that when the reverse takes
place, heat is disengaged.*
[Footnote *: This rule, if not universal, admits of very few
exceptions.]
EMILY.
We can now, I think, account for the ether boiling, and the water
freezing in vacuo, at the same temperature.†
[Footnote †: See page 102.]
MRS. B.
Let me hear how you explain it.
EMILY.
The latent heat, which the water gave out in freezing, was immediately
absorbed by the ether, during its conversion into vapour; and therefore,
from a latent state in one liquid, it passed into a latent state in the
other.
MRS. B.
But this only partly accounts for the result of the experiment; it
remains to be explained why the temperature of the ether, while in a
state of ebullition, is brought down to the freezing temperature of the
water. --It is because the ether, during its evaporation, reduces its
own temperature, in the same proportion as that of the water, by
converting its free caloric into latent heat: so that, though one liquid
boils, and the other freezes, their temperatures remain in a state of
equilibrium.
EMILY.
But why does not water, as well as ether, reduce its own temperature by
evaporating?
MRS. B.
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