Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
Though you will not allow us to enquire into the precise cause of
electricity, may we not ask in what manner the fluid acts on the metals
so as to produce it?
MRS. B.
The action of the fluid on the metals, whether water or acid be used, is
entirely of a chemical nature. But whether electricity is excited by
this chemical action, or whether it is produced by the contact of the
two metals, is a point upon which philosophers do not yet perfectly
agree.
EMILY.
But can the mere contact of two metals, without any intervening fluid,
produce electricity?
MRS. B.
Yes, if they are afterwards separated. It is an established fact, that
when two metals are put in contact, and afterwards separated, that which
has the strongest attraction for oxygen exhibits signs of positive, the
other of negative electricity.
CAROLINE.
It seems then but reasonable to infer that the power of the Voltaic
battery should arise from the contact of the plates of zinc and copper.
MRS. B.
It is upon this principle that Volta and Sir H. Davy explain the
phenomena of the pile; but notwithstanding these two great authorities,
many philosophers entertain doubts on the truth of this theory. The
principal difficulty which occurs in explaining the phenomena of the
Voltaic battery on this principle, is, that two such plates show no
signs of different states of electricity whilst in contact, but only on
being separated after contact. Now in the Voltaic battery, those plates
that are in contact always continue so, being soldered together: and
they cannot therefore receive a succession of charges. Besides, if we
consider the mere disturbance of the balance of electricity by the
contact of the plates, as the sole cause of the production of Voltaic
electricity, it remains to be explained how this disturbed balance
becomes an inexhaustible source of electrical energy, capable of pouring
forth a constant and copious supply of electrical fluid, though without
any means of replenishing itself from other sources. This subject, it
must be owned, is involved in too much obscurity to enable us to speak
very decidedly in favour of any theory. But, in order to avoid
perplexing you with different explanations, I shall confine myself to
one which appears to me to be least encumbered with difficulties, and
most likely to accord with truth.*
This theory supposes the electricity to be excited by the chemical
action of the acid on the zinc; but you are yet such novices in
chemistry, that I think it will be necessary to give you some previous
explanation of the nature of this action.
All metals have a strong attraction for oxygen, and this element is
found in great abundance both in water and in acids. The action of the
diluted acid on the zinc consists therefore in its oxygen combining with
it, and dissolving its surface.
Public-domain text, read in full here on John Shaqi.
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