Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
It was the prevailing opinion; and the difference of gas or vapour was
thought to depend on the different manner in which caloric was united
with the basis of these two kinds of elastic fluids. In vapour, it was
considered as in a latent state; in gas, it was said to be chemically
combined. But the late researches of Sir H. Davy have given rise to a
new theory respecting gasses; and there is now reason to believe that
these bodies owe their permanently elastic state, not solely to caloric,
but likewise to the prevalence of either the one or the other of the two
electricities.
EMILY.
When you speak, then, of the simple bodies oxygen and nitrogen, you mean
to express those substances which are the basis of the two gasses?
MRS. B.
Yes, in strict propriety, for they can properly be called gasses only
when brought to an aeriform state.
CAROLINE.
In what proportions are they combined in the atmosphere?
MRS. B.
The oxygen gas constitutes a little more than one-fifth, and the
nitrogen gas a little less than four-fifths. When separated, they are
found to possess qualities totally different from each other. For oxygen
gas is essential both to respiration and combustion, while neither of
these processes can be performed in nitrogen gas.
CAROLINE.
But if nitrogen gas is unfit for respiration, how does it happen that
the large proportion of it which enters into the composition of the
atmosphere is not a great impediment to breathing?
MRS. B.
We should breathe more freely than our lungs could bear, if we respired
oxygen gas alone. The nitrogen is no impediment to respiration, and
probably, on the contrary, answers some useful purpose, though we do not
know in what manner it acts in that process.
EMILY.
And by what means can the two gasses, which compose the atmospheric air,
be separated?
MRS. B.
There are many ways of analysing the atmosphere: the two gasses may be
separated first by combustion.
EMILY.
You surprise me! how is it possible that combustion should separate
them?
MRS. B.
I should previously remind you that oxygen is supposed to be the only
simple body naturally combined with negative electricity. In all the
other elements the positive electricity prevails, and they have
consequently, all of them, an attraction for oxygen.*
[Footnote *: If chlorine or oxymuriatic gas be a simple body,
according to Sir H. Davy’s view of the subject, it must be
considered as an exception to this statement; but this subject
cannot be discussed till the properties and nature of chlorine
come under examination.]
CAROLINE.
Oxygen the only negatively electrified body! that surprises me
extremely; how then are the combinations of the other bodies performed,
if, according to your explanation of chemical attraction, bodies are
supposed only to combine in virtue of their opposite states of
electricity?
MRS. B.
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