Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
But if you can take the oxygen from the metal, shall we not then have it
in its palpable simple state?
MRS. B.
No; for I can only separate the oxygen from the manganese, by presenting
to it some other body, for which it has a greater affinity than for the
manganese. Caloric affording the two electricities is decomposed, and
one of them uniting with the oxygen, restores it to the aëriform state.
EMILY.
But you said just now, that manganese would attract oxygen from the
atmosphere in which it is combined with the negative electricity; how,
therefore, can the oxygen have a superior affinity for that electricity,
since it abandons it to combine with the manganese?
MRS. B.
I give you credit for this objection, Emily; and the only answer I can
make to it is, that the mutual affinities of metals for oxygen, and of
oxygen for electricity, vary at different temperatures; a certain degree
of heat will, therefore, dispose a metal to combine with oxygen, whilst,
on the contrary, the former will be compelled to part with the latter,
when the temperature is further increased. I have put some oxyd of
manganese into a retort, which is an earthen vessel with a bent neck,
such as you see here. (PLATE VII. Fig. 2.) --The retort containing the
manganese you cannot see, as I have enclosed it in this furnace, where
it is now red-hot. But, in order to make you sensible of the escape of
the gas, which is itself invisible, I have connected the neck of the
retort with this bent tube, the extremity of which is immersed in this
vessel of water. (PLATE VII. Fig. 3.) --Do you see the bubbles of air
rise through the water?
CAROLINE.
Perfectly. This, then, is pure oxygen gas; what a pity it should be
lost! Could you not preserve it?
MRS. B.
We shall collect it in this receiver. --For this purpose, you observe,
I first fill it with water, in order to exclude the atmospherical air;
and then place it over the bubbles that issue from the retort, so as to
make them rise through the water to the upper part of the receiver.
EMILY.
The bubbles of oxygen gas rise, I suppose, from their specific levity?
MRS. B.
Yes; for though oxygen forms rather a heavy gas, it is light compared to
water. You see how it gradually displaces the water from the receiver.
It is now full of gas, and I may leave it inverted in water on this
shelf, where I can keep the gas as long as I choose, for future
experiments. This apparatus (which is indispensable in all experiments
in which gases are concerned) is called a water-bath.
CAROLINE.
It is a very clever contrivance, indeed; equally simple and useful. How
convenient the shelf is for the receiver to rest upon under water, and
the holes in it for the gas to pass into the receiver! I long to make
some experiments with this apparatus.
MRS. B.
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