Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
Water may be decomposed by means of metals without any difficulty; but
for this purpose the intervention of an acid is required. Thus, if we
add some sulphuric acid (a substance with the nature of which you are
not yet acquainted) to the water which the metal is to decompose, the
acid disposes the metal to combine with the oxygen of the water so
readily and abundantly, that no heat is required to hasten the process.
Of this I am going to shew you an instance. I put into this bottle the
water that is to be decomposed, as also the metal that is to effect that
decomposition by combining with the oxygen, and the acid which is to
facilitate the combination of the metal and the oxygen. You will see
with what violence these will act on each other.
CAROLINE.
But what metal is it that you employ for this purpose?
MRS. B.
It is iron; and it is used in the state of filings, as these present a
greater surface to the acid than a solid piece of metal. For as it is
the surface of the metal which is acted upon by the acid, and is
disposed to receive the oxygen produced by the decomposition of the
water, it necessarily follows that the greater is the surface, the more
considerable is the effect. The bubbles which are now rising are
hydrogen gas----
CAROLINE.
How disagreeably it smells!
MRS. B.
It is indeed unpleasant, though, I believe, not particularly hurtful. We
shall not, however, suffer any more to escape, as it will be wanted for
experiments. I shall, therefore, collect it in a glass-receiver, by
making it pass through this bent tube, which will conduct it into the
water-bath. (PLATE VIII. fig. 3.)
EMILY.
How very rapidly the gas escapes! it is perfectly transparent, and
without any colour whatever. --Now the receiver is full----
MRS. B.
We shall, therefore, remove it, and substitute another in its place. But
you must observe, that when the receiver is full, it is necessary to
keep it inverted with the mouth under water, otherwise the gas would
escape. And in order that it may not be in the way, I introduce within
the bath, under the water, a saucer, into which I slide the receiver, so
that it can be taken out of the bath and conveyed any where, the water
in the saucer being equally effectual in preventing its escape as that
in the bath. (PLATE VIII. fig. 4.)
EMILY.
I am quite surprised to see what a large quantity of hydrogen gas can be
produced by such a small quantity of water, especially as oxygen is the
principal constituent of water.
MRS. B.
In weight it is; but not in volume. For though the proportion, by
weight, is nearly six parts of oxygen to one of hydrogen, yet the
proportion of the volume of the gases, is about one part of oxygen to
two of hydrogen; so much heavier is the former than the latter.
CAROLINE.
But why is the vessel in which the water is decomposed so hot? As the
water changes from a liquid to a gaseous form, cold should be produced
instead of heat.
MRS. B.
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