Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
Thirty c. c. of baryta solution are run into a small flask, and the oxalic
acid run in from a Mohr’s burette with float, the vanishing-point of the
alkaline reaction being ascertained by delicate turmeric paper. As soon as
a drop placed on turmeric paper does not give a brown ring the end is
attained.
The actual analysis is performed by filling a bottle of known capacity,
with the aid of a pair of bellows, with the air to be analysed, then
distributing over its sides 45 c. c. of the baryta water it is left for
half an hour. The turbid water is poured into a cylinder, closely secured,
and allowed to deposit; then take out 30 c. c. by a pipette of the clear
fluid, run in the solution of oxalic acid, multiply the volume used by
1·5, and deduct the produce from the c. c. of oxalic acid used for 45 c.
c. of the fresh baryta water. A different method has been suggested by Dr
Angus Smith, viz. to measure the carbonic anhydride by the turbidities of
the baryta water; this is, in fact, a colorimetric test. For rough
approximative results Dr Smith’s process will be found a very useful and
convenient one. It depends upon the fact that the amount of carbonic acid
in a given quantity of air will not produce a precipitate in a given
quantity of lime or baryta water unless the carbonic acid is in excess.
The following is one of his tables:——Columns 1 and 2 give the rates of
carbonic acid in the quantity of air which will produce no precipitate in
half an ounce of lime water. Column 3 is the same as column 2; but 14·16
c. c. (half an ounce) is added to give the corresponding size of the
bottle, and column 4 gives the size of the bottle in ounces.
To be used when the point of observation is “no
precipitate.” Half an ounce of baryta water contains
about ·08 gramme of baryta.
Air at 0° C. and 760 millims. Bar.
Carbonic Acid Volume of Size of bottle Size of bottle
in the Air, Air in cubic in cubic in ounces
per cent. centimètres. centimètres. Avoirdupois.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account