Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_d._ (B. P. 1867.) Take of rectified spirit, 1 pint; carbonate of potash,
1-1/2 ounce; slaked lime, 10 ounces. Put the carbonate of potash and
spirit into a stoppered bottle and allow them to remain in contact for two
days, frequently shaking the bottle. Expose the slaked lime to a red heat
in a covered crucible for half an hour, then remove it from the fire, and,
when it has cooled, immediately put the lime into a flask or retort, and
add to it the spirit from which the denser aqueous solution of carbonate
of potash, which will have formed a distinct stratum at the bottom of the
bottle, has been carefully and completely separated. Attach a condenser to
the apparatus, and allow it to remain without any external application of
heat for twenty-four hours; then applying a gentle heat, let the spirit
distil until that which has passed over shall measure 1-1/2 fluid ounce;
reject this, and continue the distillation into a fresh receiver until
nothing more passes at a temperature of 200° Fahr.
_e._ (Poggendorff.) Saturate alcohol with caustic potash, then add half
its volume of water, and distil at a low temperature.
II. Of _Hydrated_ or _Commercial Alcohol_:——
_a._ (ALCOHOL, Ph. L. 1836.) Take of rectified spirit (sp. gr. 0·838), 1
gal.; chloride of calcium, 1 lb.; proceed as above, and distil 7 pints and
5 fl. oz. Sp. gr. of product 0·815. It contains about 7% of water, by
weight, and 5% by volume.
_b._ (ALCOHOL, Ph. D. 1826.) Rectified spirit, 1 gal.; pearl-ashes (dried
and still hot), 3-1/2 lbs.; mix, digest in a covered vessel, with frequent
agitation, for seven days; then decant the clear portion, and add to it of
chloride of calcium, 1 lb.; agitate to effect solution, and distil off the
spirit until the mixture in the retort begins to thicken. Sp. gr. of
product 0·810. It contains about 5% of water, by weight.
_c._ (Without distillation.) Rectified spirit is agitated, in a closed
vessel, with anhydrous carbonate of potash (prepared by heating the salt
to redness, and still slightly warm), until the powder sinks to the bottom
undissolved; the carbonate is then added in considerable excess, and the
agitation repeated at short intervals for some hours or even days; lastly,
after sufficient repose, the clear upper portion is decanted.——_Obs._ If a
clean spirit, and pure carbonate of potash (or at least one perfectly free
from caustic potash or any other impurity soluble in strong spirit), be
used, an alcohol sufficiently pure and free from water for many common
purposes may be thus obtained; otherwise the product contains a little
potassa, &c., which can only be removed by distillation. For some
purposes, however, this would not be objectionable. Sp. gr. about ·812.
[Illustration:
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