Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Tests in cases of death._ 1. The odour of the contents of the stomach and
ejected matters, and their ready inflammability. 2. The spirit may be
separated by digestion with water, filtration, the addition of carbonate
of potash, and distillation.
_Comp., &c._ Its per-centage composition is——
Dumas and Brande and Ure. sp.
Boullay. Ure. gr. 0·812.
Carbon 52·37 52·18 47·85
Hydrogen 13·01 13·04 12·24
Oxygen 34·61 34·78 39·91
------- -------- --------
99·99 100·00 100·00
This nearly represents 2 equivalents of carbon, 3 eq. of hydrogen, and 1
of oxygen. The atom of alcohol is now regarded as a multiple of these
numbers, and formed by the breaking up of one atom of grape sugar
(C_{13}H_{28}O_{11}) into 4 eq. of alcohol, 8 eq. of carbonic acid, and 4
eq. of water. It was formerly regarded as a compound of 1 eq. of olefiant
gas, and 1 eq. of water; but it is now generally viewed as HYDRATE OF THE
OXIDE OF ETHYLE (C_{2}H_{5}.HO), or a compound of ethylene and water
(C_{2}H_{4}.H_{2}O). Grape sugar alone yields alcohol; cane sugar, before
it undergoes the vinous fermentation, being first converted into this
substance by contact with the ferment.
_Purity._ The presence of water is shown by the specific gravity (see
ALCOHOLOMETRY); the absence of other foreign matter by the following
tests:——
1. Its colour and transparency is not affected by the addition of a little
colourless oil of vitriol (Liebig), or by a solution of nitrate of silver,
and subsequent exposure for some time to solar light (Vögel), unless
either essential oil or organic matter be present, when it assumes a
reddish tinge. 2. It should be neutral to test-papers, colourless, leave
no residue on evaporation, and be miscible, in all proportions, with water
and with ether. 3. Its boiling point should never be less than 170° Fahr.;
a lower temperature suggests the presence of wood spirits, or acetone, or
one of the ethers. To detect wood spirit (wood naphtha) see Nessler’s
Test. For the reverse of this adulteration——the evasion of the duty by the
introduction of spirit, under the disguise of naphtha, turpentine,
&c.——see those articles.
4. The presence of water in alcohol may be detected, not only by the sp.
gr., but also by white anhydrous sulphate of copper burning blue when
dropped into it. 5. Potassium placed on alcohol does not take fire, unless
a considerable per-centage of water be present.
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