Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
Every alkali work must be carried on so as to ensure the condensation of
not less than 95% of muriatic acid evolved therein; and it must be so
condensed that in each cubic foot of air, smoke, or chimney gases,
escaping from the works into the atmosphere, there is not contained more
than one fifth part of a grain of muriatic acid. Penalty for first
conviction, £50; for second and other offences, £100, or less (26 and 27
Vict., c. 124, s. 4; 37 and 38 Vict., c. 43, s. 4).
The owner of every alkali work is also bound “to use the best practicable
means of preventing the discharge into the atmosphere of all other noxious
gases arising from such work; or of rendering such gases harmless when
discharged.”
The noxious gases are defined to be sulphuric acid, sulphurous acid
(except that arising from the combustion of coals), nitric acid, or other
noxious oxides of nitrogen, sulphuretted hydrogen and chlorine (37 and 38
Vict., c. 43, ss. 5 and 8).
The owner is liable for any offence against the Alkali Acts, unless he
prove that the offence was committed by some agent, servant, or workman,
and without his knowledge, in which case the agent, &c., is liable (26 and
27 Vict., c. 124, s. 5).
Every alkali work must be registered; penalty for neglect £5 per day
(ibid., s. 6).
Powers are given to owners to make special rules for the guidance of their
workmen (ibid. s. 13).
=ALKALIM′ETRY.= _Syn._ ALKALIME′TRIA, L.; ALCALIMÉTRIE, Fr. In
_chemistry_, the estimation of the strength of the commercial alkalies;
the art or process of determining the quantity or proportion of pure
caustic alkali, or of its carbonate, in any given sample or simple
solution. It is the reverse of ‘acidimetry,’ and it should be understood
that it does not apply to alkalies occurring under any other form or
condition than those just mentioned. Alkalimetric assays are now also
frequently and conveniently extended to the estimation of the alkaline
earths and their carbonates, as hereafter noticed.
_Alkalimetrical processes._ These, like those of ‘acidimetry,’ are for
the most part founded on——the capacity of the bases to saturate acids——the
estimation of the quantity of dry carbonic acid liberated from a given
weight of an alkaline carbonate under the influence of a stronger acid;
and, in the case of the pure alkalies, the sp. gr. of their solutions.
From any one of these results the exact amount of alkali, or of alkaline
carbonate, present in a sample, is easily found or calculated. These
processes are, indeed, precisely similar to those described under
ACIDIMETRY; but here the unknown quantity sought is the alkali, instead of
the acid.
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