Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
The most convenient test-acid, or normal solution, both for commercial and
chemical assays, is perhaps dilute sulphuric acid, which, when intended to
be used VOLUMETRICALLY, has the sp. gr. 1·032 at 60° Fahr., and contains
in 100 alkalimetrical divisions 1000 water-grains measure, or 1 litre,
exactly 49 gr. (or grammes) of sulphuric acid; and when intended to be
used GRAVIMETRICALLY, or by weight, has the sp. gr. 1·033, and contains in
1000 gr. (or grammes) weight exactly 49 gr. (grammes) of sulphuric acid;
and, in both cases, consequently corresponds to 1 equiv. of every other
base. These dilute acids are easily prepared by mixing 1 part of the
concentrated acid with 11 or 12 parts of distilled water; the precise
quantity depending on the strength of the acid employed, and must be so
arranged that 1000 grains shall exactly neutralise 1000 grains of water
containing 53 grains of pure anhydrous sodium carbonate.
This acid (as well as all those hereafter mentioned) may be kept faintly
tinged with litmus, which is often more convenient than tinging the
alkaline solution at the time of making the assay.
It will at once be seen that every alkalimeter division of the first of
the above acids, and every 10 gr. of the second, represent the 1/100th
part, or 1% of alkali whenever the equivalent weight[18] of the latter is
taken for the assay. Every 1-10th part of an alkalimeter-division (or
every drop), and every grain weight (when a Schüster’s alkalimeter is
employed) then respectively represents the 1/10 of 1%; and the result
sought is obtained without the necessity of any calculation.
[Footnote 18: See Table II, at the end of this article.]
This is obvious——for if the equivalent of a pure alkali or of
its carbonate (_i. e._ one of 100%) requires an equiv. (100
alkalimeter-divisions, or 1000 gr.) of test-acid to saturate it, an alkali
or alkaline carbonate of 75%, 50%, or 25%, will respectively require only
75, 50, or 25 divisions, or 750, 500, or 250 gr.; and so of other
strengths in proportion. The only precaution necessary is always to take
the standard weight for the assay answering to the equiv. of the
denomination of the per-centage result sought. Thus, in testing a
carbonate of potash, we may either wish to determine its per-centage
richness in ‘dry carbonate,’ or in ‘pure potassa,’ the latter being
usually the case. To obtain the first, we must take 69 gr. for the assay;
and to obtain the second, 47 gr. With _CAUSTIC ALKALIES_, or mixtures
containing them, the weight, in grains, taken for the assay, must always
correspond to the equiv. of the pure base. See Table II, at the end of
this article.
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