Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
equivalents of the respective substances from which the per-centage
strength may be found by the rule of proportion, as before explained.
Thus, in the case of a 100-gr. sample of carbonate of soda which has lost
15-1/4 gr. of carbonic acid, by the assay, this would be——
22 : 31 :: 15-1/4 : 21·48%
or nearly 21-1/2 per cent. of pure soda. If 53, the equiv. of anhydrous
carbonate of soda, be taken, instead of 31 (the eq. of pure soda), the
answer would have been, in the terms of that substance, 36·748%, or nearly
36-3/4 per cent. When an aliquot part of 100 gr. has been taken for the
assay, either the result, or the third term of the proportion, must, of
course, he multiplied by the denominator and divided by the numerator of
the fraction representing such aliquot part.
By multiplying the weight of carbonic anhydride lost, by the numbers
opposite the names of the respective alkalies and their carbonates in the
second column of the following _Table_ the equivalent per-centage value of
the carbonates examined may be obtained in terms corresponding to the
various denominations named therein, when 100 gr., or any aliquot part of
100 gr., have been tested; the result, in the latter case, being, of
course, multiplied as before.
By taking certain standard weights for the assay, the quantity of carbonic
acid evolved may be made to furnish the per-centage strength or value of
the specimen in the terms of either the pure or carbonated alkalies,
whether in their anhydrous or hydrated state. The numbers in the second
column of the following _Table_ represent the quantity in grains and
decimal parts of each of the substances named in the first column,
equivalent to one grain of carbonic anhydride. These numbers, as already
mentioned, may be employed as factors for converting any numbers
representing grains of that acid into the equivalents of these substances,
true to 4 places of decimals; and further, they furnish us with the data
for determining the exact number of grains which must be tested, so that
the loss of weight in carbonic anhydride shall at once give us the
per-centage richness of the sample in the terms of the denomination for
which it is taken. The numbers in the third column of the _Table_, formed
by simply moving the decimal point of the numbers in the second column one
figure further to the right, indicate the weights to be taken for the
assay, so that the loss of weight, reckoned in tenths of a grain, exactly
represents the per-centage strength in the terms sought. The weights
corresponding to the numbers in the fifth column give the same results,
provided the loss of weight is reckoned in quarter-grains; those in the
sixth column effect the same when the loss of weight is reckoned in
half-grains; whilst those in the last column require that the gas
eliminated should be counted in grains, and are simply the numbers in the
second column of the _Table_ multiplied by 100, or reproduced by moving
the decimal point two figures to the right.
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