Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_a._ It dissolves completely; absence of strychnia; probable
presence of BRUCIA, QUINA (?), or VERATRIA:——the alcoholic
solution is evaporated to dryness, and, if quina has been
already detected, the residue is divided into two portions,
one of which is tested for Brucia, the other for Veratria.
_b._ It does not dissolve, or not completely; probable presence
of STRYCHNIA, and perhaps also of Brucia and Veratria:——the
filtered fluid is divided into two portions, and tested
separately as at _a_.
4. The original liquid 1. _a_. may contain Salicine, a proximate vegetable
principle closely allied to the alkaloids:——a portion is boiled with
hydrochloric acid for some time; the formation of a precipitate shows the
presence of SALICIN. (See 2, _below_.)[25]
[Footnote 25: For further information on this subject, see the admirable
‘System of Qual. Chem. Anal.,’ by Dr C. R. Fresenius. Churchill.]
II. (Larocque and Thibierge.) Terchloride of gold is recommended, by these
writers, as a more decisive test for the alkaloids than the ‘double
chloride of gold and sodium’ commonly employed for this purpose. The
following are the colours of the precipitates which it produces with the
aqueous solution of their salts:——BRUCIA, milk-brown, passing into
coffee-brown, and lastly chocolate-brown:——CINCHONIA, sulphur
yellow:——MORPHIA, yellow, then bluish, and lastly violet; in this last
state the gold is reduced, and the precipitate is insoluble in water,
alcohol, the caustic alkalies, and sulphuric, nitric, and hydrochloric
acid; it forms with aqua regia a solution which is precipitated by
protosulphate of iron:——QUINA, buff-coloured:——STRYCHNIA,
canary-yellow:——VERATRIA, pale greenish-yellow. All these precipitates,
with the exception mentioned, are very soluble in alcohol, insoluble in
ether, and only slightly soluble in water. Those with morphia and brucia
are sufficiently marked to prevent these alkalies from being mistaken for
each other; and those with brucia and strychnia are, in like manner,
easily distinguishable.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account