Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Prep._ Aluminum is precipitated as a hydrate from solutions of aluminum
salts on the addition of an alkali or alkaline carbonate; and this
precipitate, after being thoroughly washed and dried, on ignition loses
its water and becomes anhydrous. The following are the best formulæ for
the purpose:——
Alum is dissolved in about 20 times its weight of distilled water, and the
solution is dropped slowly into pure solution of ammonia, until the latter
is nearly but not entirely saturated, when the whole is set aside for some
time. The clear supernatant liquid is then decanted, and the precipitate
is carefully and thoroughly washed three or four times with tepid
distilled water; after which it is collected on a filter, again well
washed with water, and, lastly, pressed and dried between bibulous paper,
either without heat, or at a temperature not higher than 120° Fahr. The
product is pure hydrate of ammonium, and is converted into anhydrous
alumina by exposure to a white heat in a covered crucible. The residuum,
after ignition, is pure ANHY′DROUS ALUMINA, or SESQUIOX′IDE OF ALUMIN′UM.
A solution of alum is slowly added to a solution of carbonate of ammonia,
avoiding excess; and the resulting precipitate, after being washed and
pressed, is dried at a heat of from 120° to 180° Fahr.
_Prop., &c._ A soft white powder. The hydrate is freely soluble in the
acids and in solution of caustic potassa and soda (from which it is
precipitable by sal ammoniac); when anhydrous (as after ignition), it is
scarcely acted on by acids, and when perfectly indurated, or crystallised,
it is wholly insoluble; but on ignition with alkalies, alkaline
ALU′MINATES are formed, and the alumina is then readily dissolved by
acids, forming salts, which are mostly colourless, non-volatile, and
soluble; they have a very astringent and somewhat sweetish taste, redden
litmus paper, and lose their acids by ignition. Its most remarkable, or
rather useful property, is its strong affinity for the fibres of organic
bodies, as cotton, flax, silk, wool, &c., which are capable of taking it
from its salts; and also for organic colouring matters. Hence its great
use in dyeing, and in bleaching liquids and the preparation of lakes.
Hydrate of aluminum agitated or digested with liquids containing vegetable
colouring matter, combines with the latter, and either entirely, or to a
great extent, removes it from the solution.
Moist precipitated alumina, dried at a heat between 70° and 80°, contains
above 58% of water; dried at 212° Fahr., about 32% of water.
_Estim._ Aluminum is weighed as oxide, after ignition. The solubility of
the moist or recently precipitated hydrate in solution of ammonia enable
us to separate it from the ALKALINE EARTHS which, when present, are thrown
down with it.
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