Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
The manufacture of sal ammoniac is usually a distinct business, and is
carried on to a very great extent in the neighbourhood of London. Indeed,
the London makers now supply the chief portion of that used in England. A
large quantity is now, however, made at Manchester and Liverpool. A small
quantity is imported from Germany. That from Brunswick is in the form of
sugar-loaves. An inferior quality is also imported, in chests, from the
East Indies.
The red bands frequently seen in the sal ammoniac of commerce are said to
arise from the workmen falling asleep, and allowing the fire to go down,
and then suddenly raising the heat too high. (Muspratt.) They consist
chiefly of ammonio-chloride of iron.
=Ammonium, Citrate of.= (NH_{4})_{2}HC_{6}H_{6}O_{7}. _Syn._ DIAMMONIUM
CITRATE, CITRATE OF OXIDE OF AMMONIA; AMMON′′NIÆ CIT′RAS, L.
_Prep._ A concentrated solution of pure citric acid, gently heated, is
saturated with sesquicarbonate of ammonium, in fine powder (about 7 parts
to 6), and slightly in excess; and the resulting liquid is crystallised by
refrigeration in close vessels, or by evaporation in vacuo. If heat be
employed in the evaporation of the solution, an acid citrate will be
formed.
_Uses, &c._ Chiefly as a chemical test. An extemporaneous citrate, made
with lemon-juice and drunk effervescing, is employed as a saline draught,
and a mild aperient and diaphoretic, in fevers, &c.
=Ammonium, Ferrocyanide of.= (NH_{4})_{4} FeC_{6}N_{6} . 3Aq. _Syn._
FERROCYANATE D’AMMONIAQUE, Fr. _Prep._ 1. Saturate a solution of
hydroferrocyanic acid with sesquicarbonate of ammonium, in slight excess;
evaporate the solution at a heat below ebullition, and crystallise by
refrigeration.
2. Digest ferrocyanide of lead or of iron in a solution of sesquicarbonate
of ammonium, at a gentle heat, for some time; then filter, evaporate, and
crystallise.
_Prop., &c._ It is isomorphous with ferrocyanide of potassium; it is
easily crystallisable, very soluble in water, and is decomposed by
ebullition.
=Ammonium, Iodide of.= NH_{4}I. _Syn._ HYDRIODATE OF AMMONIA; AMMO′′NII
IODI′DUM, L.; HYDRIODATE D’AMMONIAQUE, Fr. _Prep._ An aqueous solution of
hydriodic acid is neutralised with ammonia, or ammonium sesquicarbonate,
in slight excess; and the resulting liquid is either carefully, but
rapidly, evaporated to dryness over a water bath, or it is concentrated by
the same means, and then caused to deposit crystals by refrigeration; in
both cases care is taken to keep a slight excess of ammonia present during
the evaporation. The crystals are dried by pressure between folds of
bibulous paper; and the product, in either form, preserved in a stoppered
bottle.
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