Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
1. The molecular weight of commercially pure bicarbonate of potash, in
crystals, being 100, whilst that of absolute acetic acid is 60, it is
evident that every ten grains of the bicarbonate will exactly equal 6
grains of the acid. To apply this practically, we have only to exactly
neutralise 100 gr. of the vinegar or solution under examination with the
bicarbonate, observing the usual precautions; then, as 10 is to 6, so is
the number of grains used, to the per-centage strength required. In this,
as in other like cases, it is convenient to form a test-solution with the
bicarbonate, by dissolving it in sufficient water to fill the 100
divisions of any simple form of ‘acidimeter,’ as _a_, _b_, or _c_; when
the quantity of the solution, and, consequently, of the salt used, may be
read off at once from the graduated portion of the tube. Still greater
accuracy may be obtained by dissolving the bicarbonate in exactly 1000 gr.
of distilled water contained in a ‘Schuster’s alkalimeter,’ previously
very carefully weighed; in which case each grain of the test-solution will
indicate 1/10th of a grain, or 0·1% of absolute acetic acid, whilst every
10 grains will be equal to 1 grain, or 1%.
[Illustration]
The test-solution may also be prepared from bicarbonate of soda, or from
the carbonates of soda or potash, care being taken that the quantity of
the salt dissolved be in proportion to its molecular weight.
2. (Brande.) A small piece of white marble, clean and dry, is weighed, and
then suspended by a silk thread in a weighed sample (say 100 or 1000 grs.)
of the vinegar or acid under examination; the action being promoted by
occasionally stirring the liquid with a glass rod, until the whole of the
acid is saturated, as shown by no further action on the marble being
observable on close inspection. The marble is then withdrawn, washed in
distilled water, dried and weighed. The loss in weight which it has
sustained will be nearly equal to the acetic acid present, or strictly, as
50 (marble) to 60 (absolute acetic acid). The only precautions required
are, to avoid striking the piece of marble with the rod whilst stirring
the solution, or causing loss of substance in it after its withdrawal; and
to allow ample time for the action of the acid on it. If the sample
consists of strong acid, it should be diluted with twice or thrice its
weight of water before suspending the marble in it.
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