Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
During the oxidation of the alcohol of vegetable solutions, some of the
other organic matters present also suffer change. A white gelatinous mass
(_mother of vinegar_)[5] is commonly deposited; but this is a secondary
result of the process, and not, as formerly supposed, one essential to it.
In ordinary cases acetification occurs only at or near the surface of the
liquid; which accounts for the length of time required for the operation
under the old process of ‘fielding,’ and the shorter time in which it is
accomplished by the improved process of Mr Ham. It proceeds favorably at
temperatures ranging from 60° to 90° Fahr.; and most rapidly at 95° Fahr.
(Liebig). In the ‘quick process’ of making vinegar a temperature of 90° to
92° is generally aimed at; but it often rises to 100°, or even to 105°,
Fahr. As the temperature falls acetification proceeds more slowly, and at
46 to 50° Fahr. it ceases altogether (Liebig).
[Footnote 5: It has generally been asserted that this substance contains
vibriones, and other low forms of organised life; but Mulder describes it,
under the name _mycoderma aceti_, as a plant of the order ‘fungi.’ It is
formed at the expense of the constituents of the vinegar, and often causes
whole vats of it to pass into water.]
Aldehyd (see _above_) is an exceedingly volatile substance, and easily
dissipated by a slight heat. It is, therefore, of the highest importance
to duly regulate the temperature, as well as the supply of air, during
acetification. In the ‘quick process’ of making vinegar the loss from this
cause is always considerable, and often very great. This loss may be
diminished by passing the heated air, as it escapes from the acetifier,
through a porcelain or silvered copper worm or refrigerator, set in a
chamber containing water of a temperature not higher than 40° to 45°
Fahr.; the connection being made at the _lower_ end of the worm, whilst
the upper end is open to the air. On the small scale, as in the
platinum-black process, the loss may be almost entirely prevented by
causing the upper air tube to pass through a vessel containing ice or a
freezing mixture; or by uniting it with the lower end of a Liebig’s
condenser.
In liquors undergoing the vinous fermentation, a portion of the newly
formed alcohol is invariably acetified whenever the temperature rises
above 51° Fahr.; and at a higher temperature, this proceeds with a
rapidity often highly injurious to the quality of the liquor. In this way
there is frequently a useless loss of the alcohol, which is rendered more
apparent by the incipient, and sometimes the actual, souring of the
liquor.
=ACETIM′ETRY=. _Syn._ ACETOM′ETRY; ACÉTOMÉTRIE, Fr.; ACETIME′TRIA, &c., L.
The art or process of determining the quantity of pure acetic acid in
vinegar, or in any other liquid. The plans generally adopted for this
purpose are——
I. From the saturating power of the acid, as in the common methods of
acidimetry:——
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