Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
Common hydrate of lime (freshly slaked lime), in powder, is added
gradually to the sample under examination, until it is saturated, when the
sp. gr. of the resulting clear solution of acetate of lime is taken by
Taylor’s ACETIMETER. This instrument is so adjusted and graduated as to
float at the mark on the stem called ‘proof,’ in a solution containing 5%
of absolute acetic acid (No. 24 vinegar). For vinegars stronger than proof
small weights are provided, each of which indicates an additional 5 per
cent. To ascertain the per-centage of real acid, 5% must therefore be
added to the acetimeter number. Thus, without being loaded, the
instrument, floating at the ‘proof mark,’ indicates a vinegar of 5%; with
one weight, a vinegar of 10%; with two weights, 15%, and so on. According
to this system of notation, each 5% is called a ‘vinegar.’ An acid of 10%
is said to contain two vinegars; one of 15%, three vinegars, &c. It is
also common to speak of the degrees of the acetimeter as proof or
over-proof. Thus, No. 24 vinegar is said to be proof; one of 5 acetimeter
degrees, 5 over-proof; one of 10 degrees, 10 over-proof, &c. For malt and
wine vinegars, which contain gluten and mucilage, this method is not
strictly accurate, as a portion of these substances escapes precipitation
by the lime, and consequently alters the specific gravity. A small weight
marked ‘M’ is generally supplied with the acetimeters for trying such
vinegars.
III. From the specific gravity:——
The sp. gr. of the sample (carefully determined by any of the usual
methods) is sought in one of the following Tables, when the corresponding
per-centage content of acetic acid is at once seen.
This method furnishes reliable results only with pure, or nearly pure
solutions which do not contain much above 50% of glacial acid, or which
have a sp. gr. not higher than 1·062. It is also more to be depended on
for weak solutions than strong ones. By carefully diluting a strong acid
with an equal weight, or twice or thrice its weight of water, and allowing
the mixture to again acquire its normal temperature, the sp. gr. may be
taken as a guide in all cases in which great accuracy is not required.
When such dilution is made it only becomes necessary to multiply the
indication furnished in the Tables by 2, 3, or 4, as the case may be. As,
however, authorities are not agreed as to the precise sp. gr. of the
monohydrate or glacial acid, and of its solutions, extreme accuracy must
not be expected by this method.
TABLE I.——_Adapted to the Specific Gravities of common
vinegar_. By Messrs J. and P. TAYLOR.
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